Recent progress in rare earth electron trapping materials and application to infrared detection
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摘要: 电子俘获材料在辐射剂量测定、光信息处理、光存储、红外光检测等许多技术领域具有广泛的应用。本文详细介绍了电子俘获材料的发光原理、材料种类、制备方法以及研究现状,并针对该材料在红外光检测方面的应用,提出了在室温下该材料存在红外光检测上限的观点。针对电子俘获材料存在性质不稳定及在制备过程中需用到硫化类材料易造成污染等问题,建议进一步改进材料制备方法。最后,文中指出玻璃陶瓷类电子俘获材料会有很好的发展前景,并对该种材料未来的发展前景进行了展望。Abstract: Electron trapping materials have been more widely used in the areas of radiation dosimetry, optical information processing, optical storage and infrared detection, etc.. This paper reviews the mechanism of photostimulated luminescence, material types, preparation methods and research progress of the electron trapping materials. On the basis of the applications of the materials to infrared detection, it points out that the detected infrared laser wavelength could exist a detecting threshold under the room temperature. For the shortcomings of the materials in unstable property and easy to cause environmental pollution by the sulphide in preparation processing, it suggests that the preparating method should be improved. Moreover, it emphasizes that the electron trapping materials based on glass ceramics will be promissing materials and prospects the future development of the materials.
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[1] LINDMAYE J. A new erasable optical memory[J]. Solid State Technol.,1988,31(8):135-138. [2] 徐叙瑢.发光学与发光材料[M]. 北京:化学工业出版社,2004. XU S R. Luminescence and Luminescent Materials[M]. Beijing:Chemical Industry Press,2004.(in Chinese) [3] TAKAHASHI K,KOHDA K,MIYAHARA J,et al.. Mechanism of photostimulated luminescence in BaFX∶ Eu2+(X=Cl,Br) phosphors[J]. J. Luminescence,1984,31-32(1):266-270. [4] SPAETH J M. Recent developments in X-ray storage phosphor materials[J]. Radiat. Meas.,2001,33(5):527-533. [5] SECU M,MATEI L,SERBAN T,et al.. Preparation and optical properties of BaFCl∶ Eu2+ X-ray storage phosphor[J]. Opt. Mater.,2000,15(2):115-122. [6] MENG X,WANG Y,JIN H,et al.. Colour centres and energy transfer in BaF2-xClx∶ Eu2+ phosphors[J]. J. Rare Earths,2006,24(2):129-133. [7] MENG X,WANG Y,JIN H,et al.. Study on the hole-type traps in BaFCl∶ Eu2+ phosphor[J]. J. Lumin.,2007,122-123(4):385-388. [8] LIU Z,MASSIL T,RIESEN H. Spectral hole-burning properties of Sm2+ ions generated by X-rays in BaFCl∶ Sm3+ nanocrystals[J]. Phy. Procedia,2010,3(4):1539-1545. [9] MENG X,WANG Y,HE D W. Synthesis and optical properties of BaFBr and BaFBr∶ Eu2+ nanoparticles[J].J. Nanoscience and Nanotechnoology,2010,10(4):2190-2192. [10] 李捷,韩莉. 紫外线对BaFCl∶ Eu光激励发光的增强效应[J]. 感光科学与光化学 ,2003,21(1):39-45. LI J,HAN L. The enhancement effect of ultraviolet on the photostimulated luminescence in BaFCl∶ Eu phosphor[J]. Photograp. Sci. Photochem.,2003,21(1):39-45.(in Chinese) [11] 王永生,熊光楠. BaFCl∶ Eu2+光存储过程中的温度效应[J]. 发光快报 ,1995(1):5-7. WANG Y SH,XIONG G N. Temperature effects of BaFCl∶ Eu2+ phosphors in the storage process[J]. Lumin. Infor.,1995(1):5-7.(in Chinese) [12] 熊光楠,娄素云. BaFX∶ Eu(X=Cl,Br)中电子陷阱的研究[J]. 天津理工学院学报 ,1998,14(3):1-4. XIONG G N,LOU S Y. A study on electron traps in BaFX∶ Eu(X=Cl,Br)[J]. J. Tianjin Inst. Tech.,1998,14(3):1-4.(in Chinese) [13] 徐征,王永生. 光激励发光材料BaFCl∶ Eu的制备及光电子能谱[J]. 北方交通大学学报 ,1997,21(4):445-448. XU ZH,WANG Y SH. The preparation and photo electroscopy of photostimulated luminescence materials BaFCl∶ Eu[J]. J. Northern Jiaotong Univ.,1997,21(4):445-448 (in Chinese) [14] 孙力,王永生. 电子俘获材料KCl∶ Eu2+的光存储特性研究[J]. 与红外 ,2000,30(2):117-120. SUN L,WANG Y SH. Optical storage properties of electron trapping material KCl∶ Eu2+[J]. Laser & Infrared,2000,30(2):117-120.(in Chinese) [15] de CRCER I A,DNTONI H L,BARBOZA-FLORES M,et al.. KCl∶ Eu2+ as a solar UV-C radiation dosimeter. Optically stimulated luminescence and thermoluminescence analyses[J]. J. Rare Earths,2009,27(4):579-583. [16] HASHIMA M,KOSHIMIZU M,ASAI K. Photo-stimulated luminescence of KCl∶ Eu under X-ray and ion irradiation[J]. Radi. Phys. Chem.,2009,78(12):1038-1043. [17] MEJA-URIARTE E V,BAUELOS J G,KOLOKOLTSEV O,et al.. Influence of europium nanostructure size on the emission of KBr∶ Eu2+[J]. Solid State Comm.,2009,149(11-12):445-447. [18] NAGARAJAN S,SUDARKODI R. Luminescence in KCl∶ Eu2+,Tl+ X-ray storage phosphors[J]. J. Alloys. Comp.,2009,468(1-2):558-563. [19] LVAREZ-GARC A S,PITERS T M,BARBOZA-FLORES M. UV induced afterglow of KCl∶ Eu, KBr∶ Eu and NaCl∶ Eu at low temperature[J]. Radiat. Meas.,2001,33(5):813-817. [20] KRAVETS V G. Using electron trapping materials for optical memory[J]. Opt. Mater.,2001,16(3):369-375. [21] 谢伟,王银海,胡义华,等. Y2O3∶ Eu,Dy的制备与红色长余辉发光性能研究[J]. 物理学报 ,2010,59(5):3344-3349. XIE W,WANG Y H,HU Y H,et al.. Preparation and red long-afterglow luminescence of Y2O3∶ Eu,Dy[J]. Chinese J. Phys.,2010,59(5):3344-3349.(in Chinese) [22] 王欣姿,王永生,孙力等. 新型陶瓷材料的光激励发光性质研究[J]. 中国稀土学报 ,2005,23(2):154-157. WANG X Z,WANG Y SH,SUN L,et al.. Photostimulated luminescence properties of a new kind of glass ceramics[J]. J. Chinese Rare Earth Soc.,2005,23(2):154-157.(in Chinese) [23] 姜薇薇,徐征. SrS∶ Eu,Sm光存储机理的研究[J]. 光学与光电技术 ,2008,6(2):43-48. JIANG W W,XU ZH. Preparation and characterization of optical storage material SrS∶ Eu,Sm[J]. Opt. Optoelec. Tech.,2008,6(2):43-48.(in Chinese) [24] JIANG W W,ZHENG X,ZHANG F J,et al.. Preparation of SrS∶ Eu,Sm and its photostimulated luminescence[J]. J. Mater. Pro. Tech.,2007,184(1-3):93-96. [25] 刘艳平,陈朝阳,范艳伟,等. SrS∶ Eu,Sm的制备及其光谱特性的研究[J]. 影像科学与光化学 ,2008,26(4):299-304. LIU Y P,CHEN ZH Y,FAN Y W,et al.. The study on preparation and spectrum properties of SrS∶ Eu,Sm[J]. Photogra. Sci. Photochem.,2008,26(4):299-304.(in Chinese) [26] 刘全生,张希艳,柏朝晖,等. SrS∶ Eu,Sm荧光粉的制备及性能表征[J]. 光谱学与光谱分析 ,2009,29(03):769-772. LIU Q SH,ZHANG X Y,BAI ZH H,et al.. Preparation and characterization of SrS∶ Eu,Sm Phosphor[J]. Spectro. Spect. Anal.,2009,29(03):769-772.(in Chinese) [27] 王玉霞,刘全生,柏朝晖,等. SrS∶ Eu,Sm的制备与光谱性能[J]. 硅酸盐通报 ,2008,27(4):677-680 WANG Y X,LIU Q SH,BAI ZH H,et al.. Preparation and spectroscopic property of SrS∶ Eu,Sm[J]. Bull. Chin. Cera. Soc.,2008,27(4):677-680.(in Chinese) [28] 姜薇薇,徐征,张希艳. CaS∶ Eu,Sm光存储材料的光谱特性[J]. 光谱学与光谱分析 ,2007,12(7):2389-2392. JIANG W W,XU ZH,ZHANG X Y. Spectral characteristics of optical storage material CaS∶ Eu,Sm[J]. Spectro. Spect. Anal.,2007,12(7):2389-2392.(in Chinese) [29] 刘秋江,陈朝阳,范艳伟,等. CaS∶ Ce,Sm材料光致荧光辐射剂量相关性能测量[J]. 原子能科学技术 ,2007,4(7):390-393. LIU Q J,CHEN ZH Y,FAN Y W,et al.. Performance test of CaS∶ Ce,Sm material related to optically stimulated luminescence dosimeter[J]. Atomic Energy Sci. Tech.,2007,4(7):390-393.(in Chinese) [30] 刘艳平,陈朝阳,范艳伟,等. 荧光材料SrS∶ Eu,Sm在辐射剂量测量中的应用[J]. 中国稀土学报 ,2008,113(3):381-384. LIU Y P,CHEN ZH Y,FAN Y W,et al.. Application of optically stimulated luminescence material SrS∶ Eu,Sm in radiation dose measurement[J]. J. Rare Earths,2008,113(3):381-384.(in Chinese) [31] 潘华强,黄丽清,童慧敏,等. 电子俘获材料CaS∶ Eu,Sm光谱特性研究[J]. 光子学报 ,2007,11(8):2083-2086. PAN H Q,HUANG L Q,TONG H M,et al.. Spectral characteristics of electron trapping material CaS∶ Eu,Sm[J]. Acta Photo. Sin.,2007,11(8):2083-2086.(in Chinese) [32] LIU Y,CHEN Z,BA W,et al.. Optically stimulated luminescence dosimeter based on CaS∶ Eu,Sm[J]. Nuclear Sci. Tech.,2008,19(2):113-119. [33] 范艳伟,陈朝阳,巴维真,等. CaS∶ Eu,Sm的制备及发光特性[J]. 功能材料 ,2007,38(A01):223-229. FAN Y W,CHEN ZH Y,BA W ZH,et al.. Preparation and fluorescent properties of CaS∶ Eu,Sm[J]. Func. Mater.,2007,38(A01):223-229.(in Chinese) [34] 卢利平,张希艳,柏朝晖,等. 低温燃烧合成红外响应材料CaS∶ Eu,Sm及性能表征[J]. 稀有金属材料与工程 ,2006,35(8):1211-1214. LU L P,ZHANG X Y,BAI ZH H,et al.. Synthesis of IR sensitive material CaS∶ Eu,Sm by low-temperature combustion and its characterization[J]. Rare Metal Mater. Eng.,2006,35(8):1211-1214.(in Chinese) [35] SINGH V,AO T K G,HU J J,et al.. uminescence and defect studies of Ce3+ doped CaS phosphor synthesized via solid state diffusion method[J]. Mater. Sci. Eng. B,2006,131(1-3):195-199. [36] DUAN X,HUANG S,YOU F,et al.. Hydrothermal preparation and persistence characteristics of nanosized phosphor SrS∶ Eu2+,Dy3+[J]. J. Rare Earths,2009,27(1):43-48. [37] NANTO H,IKEDA M,KADOTA M,et al.. Photostimulated luminescence in CaS∶ Eu,Sm phosphor ceramics induced by excitation with ionizing radiation[J]. Nuclear Instr. Meth. Phys. Res. Sec. B:Beam Interactions with Mater. Atoms,1996,116(1-4):262-264. [38] 张希艳,刘全生,王晓春,等. 红外上转换材料CaS∶ Eu,Sm的制备[J]. 红外与毫米波学报 ,2005,24(4):301-303. ZHANG X Y,LIU Q SH,WANG X CH,et al.. Preparation of infrared up-conversion material CaS∶ Eu,Sm[J]. J. Infra. Mill. Waves,2005,24(4):301-303.(in Chinese) [39] 张希艳,米晓云,柏朝晖,等. CaS∶ Eu,Sm的微波合成与发光性能研究[J]. 稀有金属材料与工程 ,2007,36(11):1996-1999. ZHANG X Y,MI X Y,BAI ZH H,et al. Microwave synthesis and luminescence properties of CaS∶ Eu,Sm[J]. Rare Metal Mater. Eng.,2007,36(11):1996-1999.(in Chinese) [40] 谢大兵,华文深,王运波,等. ZnS∶ Cu,Pb,Mn红外上转换薄膜的制备及其光谱特性研究[J]. 红外技术 ,2009,31(08): 461-466. XIE D B,HUA W SH,WANG Y B,et al.. Preparation and spectral properties of infrared up-conversion thin film ZnS∶ Cu,Pb,Mn[J]. Infra. Tech.,2009,31(08):461-466.(in Chinese) [41] 谢大兵,华文深,李刚,等. 电子俘获材料ZnS∶ Cu,Pb,Mn发光机理研究[J]. 科学技术与工程 ,2010,10(5):1144-1148. XIE D B,HUA W SH,LI G,et al.. Luminescence mechanism of electron trapping material ZnS∶ Cu,Pb,Mn[J]. Sci. Tech. Eng.,2010,10(5):1144-1148.(in Chinese) [42] 张希艳,卢利平,米晓云,等. 硫化物基荧光粉的表面包覆及性能研究[J]. 长春理工大学学报(自然科学版) ,2007,4(6):1-3. ZHANG X Y,LU L P,MI X Y,et al.. Surface coating and characterization of sulfide phosphor[J]. J. Changchun Univ. Sci. Tech.,2007,4(6):1-3.(in Chinese) [43] DO H S,KIM E J,HONG S H. Improved moisture resistance of SrS∶ Eu2+ phosphors with nanoscale SiO2 coating[J]. J. Lumin.,2010,130(8):1400-1408. [44] AVCI N,CIMIERI I,SMET P F,et al.. Stability improvement of moisture sensitive CaS∶ Eu2+ micro-particles by coating with sol-gel alumina[J]. Opt. Mater.,2010,47(3):1-4. [45] 武翠琴,张向东,王兴治,等. 基于红外上转换原理的MCP-PMT位敏探测器组件研究[J]. 光子学报 ,2009,38(5):1096-1100. WU C Q,ZHANG X D,WANG X ZH,et al.. MCP-PMT position-sensitive-device module based on IR-upconversion[J]. Acta Photo. Sin.,2009,38(5):1096-1100.(in Chinese) [46] 谢大兵,华文深,刘秉琦,等. 基于红外上转换原理的短波红外阵列探测器研究[J]. 红外技术 ,2010,205(1):6-10. XIE D B,HUA W SH,LIU B Q,et al.. Short wave infrared detector array based on IR up-conversion[J]. Infra. Tech.,2010,205(1):6-10.(in Chinese) [47] 王运波,刘秉琦,王金玉,等. 利用电子俘获材料研制复合型短波红外探测器[J]. 光学技术 2009,35(4):483-485. WANG Y B,LIU B Q,WANG J Y,et al.. Research on compound short wave infrared detector by electron trapping material[J]. Opt. Tech.,2009,35(4):483-485.(in Chinese) [48] 王震生. 电子俘获材料在夜视领域的应用[J]. 天津科技 ,2007,34(4):29-33. WANG ZH SH. Application of electron trapping materials in the field of night vision[J]. Tianjin Sci. Tech.,2007,34(4):29-33.(in Chinese) [49] 余华,熊光楠,马骏,等. 无机晶体材料中色心的形成及其存储机理的研究[J]. 天津理工学院学报 ,2001,17(1):18-23. YU H,XIONG G N,MA J,el al.. Creation of color center and mechanism of storage in inorganic material[J]. J. Tianjin Ins. Tech.,2001,17(1):18-23.(in Chinese) [50] CHEN R. Glow curves with general order kinetics[J]. J. Electrochem. Soc.,1969,166(4):1254-1259. [51] KITIS G,PAGONIS V. Peak shape methods for general order thermoluminescence glow-peaks:a reappraisal[J]. Nuclear Instr. Meth. Phys. Res. Sec. B:Beam Interactions with Mater. Atoms,2007,262(2):313-322.
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