基于半导体性单壁碳纳米管/富勒烯异质结的高性能透明全碳光电探测器

张罗茜; 尹欢; 陈越; 朱明奎; 苏言杰

doi:10.37188/CO.2022-0243

基于半导体性单壁碳纳米管/富勒烯异质结的高性能透明全碳光电探测器

上海交通大学电子信息与电气工程学院薄膜与微细技术教育部重点实验室, 上海200240

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中图分类号: TN15
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出版历程
- 收稿日期: 2022-11-24
- 修回日期: 2022-12-12
- 网络出版日期: 2023-04-04

High-performance transparent all-carbon photodetectors based on the semiconducting single-walled carbon nanotube/fullerene heterojunctions

doi: 10.37188/CO.2022-0243

Key Laboratory of Film and Microfabrication (Ministry of Education), School of Electronics, Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Funds: Supported by the National Natural Science Foundation of China (No. 61974089)

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Author Bio:
ZHANG Luo-xi (1997—), female, from Anyang, Henan Province, master degree, graduated fromJilin University with a bachelor degree in 2016, and obtained a master degreefrom Shanghai Jiaotong University in 2023, mainly engaged in the research of carbonnanotubes, optoelectronic devices and other fields. E-mail: luoxi-zhang@sjtu.edu.cn

SU Yan-jie (1982—), male, from Shangqiu, Henan Province, Ph.D., associate researcher/doctoral supervisor, obtained his Ph.D. from Shanghai Jiaotong University in 2012, mainly engaged in the research of nanomaterials and devices. E-mail: yanjiesu@sjtu.edu.cn

Corresponding author: yanjiesu@sjtu.edu.cn

摘要

摘要:
利用半导体性单壁碳纳米管（SWCNT）的高吸收系数、优异的光电特性和高载流子迁移率等特点，本文构筑了基于半导体SWCNT（sc-SWCNT）/富勒烯（C₆₀）异质结的透明全碳宽光谱的场效应晶体管光电探测器。该器件的大部分结构均由碳基材料组成，全碳异质结作为导电沟道材料，金属性SWCNT作为源漏电极，氧化石墨烯（GO）作为介质层，在可见光波段的透光率均高于80%。电学测试结果表明：该光电探测器表现出了较强的栅控能力，实现了从405~1064 nm的可见光-近红外宽光谱响应，在5 mW/cm²的940 nm 照射下，该器件光电响应率可以达到18.55 A/W，比探测率达到5.35×10¹¹ Jones，同时，表现出了优异的循环稳定性。
- 单壁碳纳米管 /
- 富勒烯 /
- 全碳异质结 /
- 高透明度 /
- 场效应晶体管光电探测器
Abstract:
Taking advantage of the high absorption coefficient, excellent photoelectric properties, and high carrier mobility of Single-Walled Carbon NanoTubes (SWCNTs), high-performance, transparent, all-carbon Field-Effect Transistor (FET) photodetector has been constructed with a high transmittance more than 80% in the visible light band, in which semiconducting SWCNT (sc-SWCNT)/fullerene (C₆₀) heterojunctions as the channel materials, patterned metallic SWCNT film as source/drain electrodes, graphene oxide (GO) as the dielectric layer, and Indium Tin Oxide (ITO) as a transparent gate electrode. The electrical test results show that the photodetector exhibits a strong gate-tunable characteristics, and achieves a broadband spectral response from 405 to 1064 nm in the visible-near infrared spectral region. Under 940 nm illumination with a light density of 5 mW/cm², the maximum photoelectric responsivity of 18.55 A/W and a specific detectivity of 5.35×10¹¹ Jones can be achieved.
- single-walled carbon nanotubes /
- Fullerene /
- all-carbon heterojunctions /
- high transparency /
- field-effect transistor photodetector

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图 1 (a)器件结构示意图和(b)器件在可见光波段的透射率

Figure 1. (a) Schematic diagram of the device structure. (b) Transmittance of the device in visible band

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图 2 (a)旋涂法沉积的sc-SWCNT薄膜、(b) sc-SWCNT/C₆₀异质结复合薄膜和(c)金属性SWCNT薄膜的扫描电子显微镜图

Figure 2. Scanning electron microscope images of (a) sc-SWCNT film deposited by spin coating, (b) sc-SWCNT/C₆₀ heterogeneous composite film and (c) m-SWCNT film

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图 3 sc-SWCNT/C₆₀薄膜的拉曼统计分析。在514 nm 辐照下(a) sc-SWCNT (黑色)和(b) sc-SWCNT/C₆₀ (蓝色)的拉曼光谱

Figure 3. Raman statistical analysis of sc-SWCNT /C₆₀ film. Raman spectra of (a) sc-SWCNT (black) and (b) sc-SWCNT /C₆₀ (blue) under 514 nm laser irradiation

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图 4 全碳器件的(a)I_ds-V_gs曲线和(b)I_ds-V_ds曲线

Figure 4. (a) I_ds-V_gs curve and (b) I_ds-V_ds curve of the all-carbon device

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图 5 全碳异质结器件在不同波长（405, 514, 650, 780, 860, 940, 1064 nm）照射下的(a) I_ds-V_ds 和(b) I_ds-T曲线

Figure 5. (a) I_ds-V_ds curve and (b) I_ds-T curve of the all-carbon device under 405, 514, 650, 780, 860, 940, 1064 nm laser irradiation

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参考文献(32)

[1]	Richter M, T Heumüller, Matt G J, et al. Carbon photodetectors: The versatility of carbon allotropes[J]. Advanced Energy Materials, 2016, 7(10): 1601574.
[2]	Murata T, Asahi S, Sanguinetti S, et al. Infrared photodetector sensitized by InAs quantum dots embedded near an Al_0.3Ga_0.7As/GaAs heterointerface[J]. Scientific Reports, 2020, 10(1): 1-11. doi: 10.1038/s41598-019-56847-4
[3]	Xing J, Zhao K, Lu H B, et al. Visible-blind, ultraviolet-sensitive photodetector based on SrTiO3 single crystal[J]. Optics Letters, 2007, 32(17): 2526-2528. doi: 10.1364/OL.32.002526
[4]	Hirsch A. The era of carbon allotropes[J]. Nature Materials, 2010, 9: 868-871. doi: 10.1038/nmat2885
[5]	Dinadayalane T C, Leszczynski J. Remarkable diversity of carbon–carbon bonds: structures and properties of fullerenes, carbon nanotubes, and graphene[J]. Structural Chemistry, 2010, 21(6): 1155-1169. doi: 10.1007/s11224-010-9670-2
[6]	Premkumar T, Mezzenga R, Geckeler K E. Carbon nanotubes in the liquid phase: Addressing the issue of dispersion[J]. Small, 2012, 8(9): 1299-1313. doi: 10.1002/smll.201101786
[7]	Cai B F, Yin H, Huo T T, et al. Semiconducting single-walled carbon nanotube/graphene van der Waals junctions for highly sensitive all-carbon hybrid humidity sensors[J]. Journal of Materials Chemistry C, 2020, 8(10): 3386-3394. doi: 10.1039/C9TC06586E
[8]	Huo T T, Yin H, Zhou D Y, et al. Self-powered broadband photodetector based on single-walled carbon nanotube/GaAs heterojunctions[J]. ACS Sustainable Chemistry &Engineering, 2020, 8(41): 15532-15539.
[9]	Ramuz M P, Vosgueritchian M, Wei P, et al. Evaluation of solution-processable carbon-based electrodes for all-carbon solar cells[J]. ACS Nano, 2012, 6(11): 10384-10395. doi: 10.1021/nn304410w
[10]	Baughman R H, Zakhidov A A, Heer W. Carbon nanotubes-The route toward applications[J]. Science, 2002, 297(5582): 787-792. doi: 10.1126/science.1060928
[11]	Schnorr J M, Swager T M. Emerging applications of carbon nanotubes[J]. Chemistry of Materials, 2011, 23(3): 646-657. doi: 10.1021/cm102406h
[12]	Chichak K S, Star A, Altoé M V P, et al. Single‐walled carbon nanotubes under the influence of dynamic coordination and supramolecular chemistry[J]. Small, 2005, 1(4): 452-461. doi: 10.1002/smll.200400070
[13]	D'Souza F, Chitta R, Sandanayaka A S D, et al. Supramolecular carbon nanotube-fullerene donor-acceptor hybrids for photoinduced electron transfer[J]. Journal of the American Chemical Society, 2007, 129(51): 15865-15871. doi: 10.1021/ja073773x
[14]	Long M, Wang P, Fang H, et al. Progress, challenges, and opportunities for 2D material-based photodetectors[J]. Advanced Functional Materials, 2019, 29(19): 1803807. doi: 10.1002/adfm.201803807
[15]	Zeng Q, Wang S, Yang L, et al. Carbon nanotube arrays based high-performance infrared photodetector[J]. Optical Materials Express, 2012, 2(6): 839-848. doi: 10.1364/OME.2.000839
[16]	Liu Y, Wei N, Zeng Q, et al. Room temperature broadband infrared carbon nanotube photodetector with high detectivity and stability[J]. Advanced Optical Materials, 2016, 4(2): 238-245. doi: 10.1002/adom.201500529
[17]	Saran R, Curry R J. Solution processable 1D fullerene C₆₀ crystals for visible spectrum photodetectors[J]. Small, 2018, 14(11): 1703624. doi: 10.1002/smll.201703624
[18]	Yin H, Zhang L, Zhu M, et al. High-Performance Visible–Near-Infrared Single-Walled Carbon Nanotube Photodetectors via Interfacial Charge-Transfer-Induced Improvement by Surface Doping[J]. ACS Applied Materials &Interfaces, 2022, 14(38): 43628-43636.
[19]	Cheng S H, Weng T M, Lu M L, et al. All carbon-based photodetectors: an eminent integration of graphite quantum dots and two-dimensional graphene[J]. Scientific Reports, 2013, 3(1): 1-7.
[20]	Park S, Kim S J, Nam J H, et al. Significant Enhancement of Infrared Photodetector Sensitivity Using a Semiconducting Single‐Walled Carbon Nanotube/C₆₀ Phototransistor[J]. Advanced materials, 2015, 27(4): 759-765. doi: 10.1002/adma.201404544
[21]	Yu X, Dong Z, Yang J K W, et al. Room-temperature mid-infrared photodetector in all-carbon graphene nanoribbon-C₆₀ hybrid nanostructure[J]. Optica, 2016, 3(9): 979-984. doi: 10.1364/OPTICA.3.000979
[22]	Zhou Z, Ding Y, Ma H, et al. Bilayer nanocarbon heterojunction for full-solution processed flexible all-carbon visible photodetector[J]. APL Materials, 2019, 7(3): 031501. doi: 10.1063/1.5054774
[23]	Itkis M E, Borondics F, Yu A, et al. Bolometric infrared photoresponse of suspended single-walled carbon nanotube films[J]. Science, 2006, 312(5772): 413-416. doi: 10.1126/science.1125695
[24]	Huo T, Zhang D, Shi X, et al. High-performance self-powered photodetectors based on the carbon nanomaterial/GaAs vdW heterojunctions[J]. Chinese Optics, 2022, 15(2): 373. (in Chinese)
[25]	Dresselhaus M S, Dresselhaus G, Saito R, et al. Raman spectroscopy of carbon nanotubes[J]. Physics Reports, 2005, 409(2): 47-99. doi: 10.1016/j.physrep.2004.10.006
[26]	Farhat H, Son H, Samsonidze G G, et al. Phonon softening in individual metallic carbon nanotubes due to the Kohn anomaly[J]. Physical Review Letters, 2007, 99(14): 145506. doi: 10.1103/PhysRevLett.99.145506
[27]	Das A, Sood A K, Govindaraj A, et al. Doping in carbon nanotubes probed by Raman and transport measurements[J]. Physical Review Letters, 2007, 99(13): 136803. doi: 10.1103/PhysRevLett.99.136803
[28]	Hatting B, Heeg S, Ataka K, et al. Fermi energy shift in deposited metallic nanotubes: A Raman scattering study[J]. Physical Review B, 2013, 87(16): 165442. doi: 10.1103/PhysRevB.87.165442
[29]	Wroblewska A, Gordeev G, Duzynska A, et al. Doping and plasmonic Raman enhancement in hybrid single walled carbon nanotubes films with embedded gold nanoparticles[J]. Carbon, 2021, 179: 531-540. doi: 10.1016/j.carbon.2021.04.079
[30]	Wang F, Dukovic G, Brus L E, et al. The optical resonances in carbon nanotubes arise from excitons[J]. Science, 2005, 308(5723): 838-841. doi: 10.1126/science.1110265
[31]	Maciel I O, Anderson N, Pimenta M A, et al. Electron and phonon renormalization near charged defects in carbon nanotubes[J]. Nature Materials, 2008, 7(11): 878-883. doi: 10.1038/nmat2296
[32]	Das A, Sood A K. Renormalization of the phonon spectrum in semiconducting single-walled carbon nanotubes studied by Raman spectroscopy[J]. Physical Review B, 2009, 79(23): 235429. doi: 10.1103/PhysRevB.79.235429