Apr. 2019

Article Contents

Chinese Optics> 2019> 12(2): 302-309.

ZHU Bo, GAO Yong-wei, LIU Zhi-chen, LUO Ya-nan. [Cd(p-nitrobenzoic acid)2(en)H2O] coordination compound in structure and fluorescent property[J]. Chinese Optics, 2019, 12(2): 302-309. doi: 10.3788/CO.20191202.0302

Citation:

ZHU Bo, GAO Yong-wei, LIU Zhi-chen, LUO Ya-nan. [Cd(p-nitrobenzoic acid)₂(en)H₂O] coordination compound in structure and fluorescent property[J].Chinese Optics, 2019, 12(2): 302-309.doi:10.3788/CO.20191202.0302

Citation:

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[Cd(p-nitrobenzoic acid)₂(en)H₂O] coordination compound in structure and fluorescent property

doi:10.3788/CO.20191202.0302

College of Chemical and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 132022, China

Funds:

National Natural Science Foundation20831002

National Natural Science Foundation21531003

Major Project in Jilin Institute of Chemical Technology2018021

Open Project of State Key Laboratory of Inorganic Synthesis & Preparative Chemistry of Jilin University2019-13

More Information

Corresponding author:E-mail:yanan_meimei@163.com
Received Date:16 Jan 2019
Rev Recd Date:01 Feb 2019
Publish Date:01 Apr 2019

Abstract

Abstract

In this paper, a new coordination polymer of[Cd(p-nitrobenzoic acid) ₂(en)H ₂O]( 1) was synthesized, based on CdCl ₂, p-nitrobenzoic acid and ethylenediamine(en), and its structure was analyzed. First, a compound(compound 1) was hydrothermally synthesized. Second, compound 1was structurally measured using single-crystal X-ray diffraction. Then, compound 1was structurally characterized using infrared spectrometry(IR), elemental analysis, power X-ray diffraction(PXRD) and thermogravimetric analysis(TGA). Finally, the fluorescence property of compound 1was measured at room temperature. Experimental results indicate that compound 1was linked into a three-dimensional(3D) supramolecular structure by N-H…O、O-H…O and C-H…O hydrogen bonds. Compound 1demonstrated fluorescent properties. Its peak of excitation was 266 nm and its peaks of emission were 377 nm and 444 nm. The fluorescent properties of compound 1mainly come from the transition from the ligand to ligand. Compound 1may be a fluorescent material with potential for further development.
- p-nitrobenzoic acid,
- hydrogen bonds,
- supramolecular structure

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References (14)

References

[1]	张旭霞, 李斌, 张黎明, 等.有机-无机复合纳米材料的传感应用及机理[J].中国光学, 2015, 8(4):651-666. //www.illord.com/CN/abstract/abstract9330.shtml ZHANG X X, LI B, ZHANG L M, et al.. Sensing application and mechanism of organic-inorganic nanocomposites[J]. Chinese Optics, 2015, 8(4):651-666. (in Chinese) //www.illord.com/CN/abstract/abstract9330.shtml
[2]	魏小平, 梁顺超, 黄文刚, 等.镍配合物分子印迹光电流型传感器的研究[J].分析化学, 2016, 44(3):348-354. http://d.old.wanfangdata.com.cn/Periodical/fxhx201603005 WEI X P, LIANG SH CH, HUANG W G, et al.. Study on molecularly imprinted sensor based on photocurrent response for Ni-complex[J]. Chinese Journal ofAnalytical Chemistry, 2016, 44(3):348-354. (in Chinese) http://d.old.wanfangdata.com.cn/Periodical/fxhx201603005
[3]	魏巧华, 韩李静, 段亚男, 等.铱配合物的电致化学发光性能研究[J].分析化学, 2011, 39(7):1109-1112. http://d.old.wanfangdata.com.cn/Periodical/fxhx201107028 WEI Q H, HAN L J, DYAN Y N, et al.. Electrochemiluminescence of two Iridium(Ⅲ) complexes[J]. Chinese Journal of Analytical Chemistry, 2011, 39(7):1109-1112. (in Chinese) http://d.old.wanfangdata.com.cn/Periodical/fxhx201107028
[4]	谢伟玲, 杨培慧, 蔡继业.锗(Ⅳ)-槲皮素配合物的制备、表征及其抗氧化活性测定[J].分析化学, 2010, 38(12): 1809-1812. http://www.cnki.com.cn/Article/CJFDTotal-FXHX201012034.htm XIE W L, YANG P H, CAI J Y. Synthesis, characterization and antioxidation activity of Germanium(Ⅳ)-quercetin complex[J]. Chinese Journal ofAnalytical Chemistry, 2010, 38(12):1809-1812. (in Chinese) http://www.cnki.com.cn/Article/CJFDTotal-FXHX201012034.htm
[5]	WU L, GUO X L, WANG Z J, et al.. Syntheses, crystal structure, and fluorescent property of a new (4, 10)-connected 3D Cd(Ⅱ) coordination polymer[J]. Chemistry Letters, 2015, 44(4):451-453. doi:10.1246/cl.141146
[6]	LAN A J, PADMANABHAN M, LI K H, et al.. Two-dimensional coordination polymers of Zn(Ⅱ) and Cd(Ⅱ) derived from 3, 3', 5, 5'-azobenzenetetracarboxylic acid exhibiting solvent facilitated structure reversibility[J]. Inorganica Chimica Acta, 2011, 366(1):68-75. doi:10.1016/j.ica.2010.10.009
[7]	罗亚楠, 姜慧莹, 刘旭影, 等.配合物Zn(5-硝基-8-羟基喹啉) 2的合成、结构及荧光性质[J].化学试剂, 2015, 37(12):1113-1117. http://www.cnki.com.cn/Article/CJFDTotal-HXSJ201512018.htm LUO Y N, JIANG H Y, LIU X Y, et al.. Synthesis, structure and fluorescent property of coordination polymer of[Zn(5-nitro-8-hydroxyquinoline) 2] [J]. Chemical Reagents, 2015, 37(12):1113-1117. (in Chinese) http://www.cnki.com.cn/Article/CJFDTotal-HXSJ201512018.htm
[8]	WU T, XU H Y, KONG F Z, et al.. Synthesis and structure of a Mn(Ⅱ)-triazolyl coordination polymer consisting of dinuclear units[J]. Chinese ofJournal Structural Chemistry, 2012, 31:1557-1562. http://www.cnki.com.cn/Article/CJFDTotal-JGHX201211006.htm
[9]	LIU W L, YU J H, JIANG J X, et al.. Hydrothermal syntheses, structures and luminescent properties of Zn(Ⅱ) coordination polymers assembled with benzene-1, 2, 3-tricarboxylic acid involving in situ ligand reactions[J]. Crystal Engineering Communications, 2011, 13(7):2764-2773. doi:10.1039/c0ce00950d
[10]	尤莉艳, 李丹, 马朝红.邻菲罗啉对苯二甲酸金属配合物的合成及表征[J].科学技术创新, 2017, 34:67-68. http://www.cnki.com.cn/Article/CJFDTOTAL-HLKX201734040.htm YOU L Y, LI D, MA CH H. Synthesis and characterization of phloroline terephthalic acid metal complexes[J]. Scientific and Technological Innovation Information, 2017, 34:67-68. http://www.cnki.com.cn/Article/CJFDTOTAL-HLKX201734040.htm
[11]	DEMET O, DURSUN A K, ONUR S, et al.. Synthesis and characterization of boric acid mediated metal-organic frame-works based on trimesic acid and terephthalic acid[J]. Journal ofMolecular Structure, 2017, 1141:261-267. http://www.sciencedirect.com/science/article/pii/S002228601730426X
[12]	苏雅静, 樊婷婷, 张美娜, 等. 4, 4'-联吡啶桥联的链状Zn(Ⅱ)配合物:合成、晶体结构和对Tb(Ⅲ)离子的荧光敏化[J].光谱学与光谱分析, 2018, 7:2170-2174. http://www.cnki.com.cn/Article/CJFDTotal-GUAN201807035.htm SU Y J, FAN T T, ZHANG M N, et al.. 4, 4'-Bipyridine bridged chain Zn(Ⅱ) complex:synthesis, crystal structure and fluorescence sensitization for Tb(Ⅲ) ion[J]. Spectroscopy and Spectral Analysis, 2018, 7:2170-2174. http://www.cnki.com.cn/Article/CJFDTotal-GUAN201807035.htm
[13]	SHELDRICK G M, SHELXTL N T. Crystal Structure Analysis Package[C]. Version 5. 10;Bruker AXS, Analytical X-ray System: Madison, WI, 1999.
[14]	DOLOMANOV O V, BOURHIS L J, GILDEA R J, et al.. OLEX2:A complete structure solution, refinement and analysis program[J]. Journal ofApplied Crystallography, 2009, 42:339-341. http://d.old.wanfangdata.com.cn/NSTLQK/NSTL_QKJJ027847152/