Research progress on organic self-assembling low-dimensional circularly polarized luminescent materials
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摘要:具有圆偏振发光（CPL）性质的材料由于在3D显示、光学存储以及光学防伪等领域的重要应用，近年来越来越受到研究人员的关注。超分子策略能够将不同类型的分子组装成具有独特功能的低维（零维、一维和二维等）结构，因而成为构筑CPL活性有机低维材料的最有效方法之一。本文从超分子自组装驱动力的角度综述了近几年自组装CPL活性有机低维材料的研究进展。首先，本文系统地总结了现阶段设计自组装CPL活性有机低维材料的策略，其次重点讨论了这类材料的性能及应用，最后探讨了这一领域未来的发展机遇和挑战。Abstract:In recent years, materials with Circularly Polarized Luminescence (CPL) have received growing attention due to their wide applications in 3D displays, optical storage, optical security, etc. Supramolecular self-assembling is one of the most effective methods to construct CPL active materials, which can assemble different types of molecules into low-dimensional (0D, 1D and 2D) structures with unique functions. This review summarizes the research progress of self-assembled CPL active organic low-dimensional materials from recent years with emphasis on the driving force of supramolecular self-assembly. Firstly, the review systematically summarizes the current design strategies of self-assembled CPL active organic low-dimensional materials. Secondly, it focuses on their performance and applications. Finally, it discusses the future opportunities and challenges of this rapidly developing field.
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图 1多重氢键参与的共组装过程。（a）B-DNA结构中的多重氢键。（b）羧酸和吡啶类粘合剂之间的双重氢键能够形成手性纳米结构。（c）芳香族氨基酸和粘合剂的化学结构[25]
Figure 1.The co-assembly process with multiple hydrogen bonds. (a) Multiple hydrogen bonds in B-DNA structures. (b) The double hydrogen bond between carboxylic acids and pyridine-based binders can form chiral nanostructures. (c) The chemical structures of aromatic amino acids and binders[25]
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