非线性光限幅材料原理、性能表征及研究进展 -

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非线性光限幅材料原理、性能表征及研究进展

doi:10.37188/CO.2021-0195

吕泽^{1, 4,},
方佑^{1, 4},
冯迢^{3, 4},
宗楠^{1, 2,,},
李云飞^3,,,
张申金^{1, 2,,},
谢政³,
彭钦军^{1, 2}

1.
中国科学院理化技术研究所固体重点实验室, 北京 100190
2.
中国科学院理化技术研究所功能晶体与技术重点实验室, 北京 100190
3.
中国科学院理化技术研究所光化学转换和功能材料重点实验室, 北京 100190
4.
中国科学院大学, 北京 100049

基金项目:国家自然科学基金重大项目（No. 51890864）；中科院理化所所长基金（No. E0A8053H12）

详细信息

作者简介:
吕　泽（1997—），女，山西运城人，博士研究生，2019年于北京化工大学获得学士学位，主要从事中红外全固态器方面的研究。E-mail：lvze191@mails.ucas.ac.cn
宗　楠（1982—），女，辽宁阜新人，博士，副研究员，2010年于中科院物理研究所获得博士学位，主要从事新型全固态及非线性频率变换技术研究。E-mail：zongnan@mail.ipc.ac.cn
李云飞（1993—），男，山西晋城人，博士，博士后，2020年于中国科学院理化技术研究所获得博士学位，主要从事非线性光学材料方向研究。E-mail：liyunfei@mail.ipc.ac.cn
张申金（1978—），男，山东新泰人，博士，研究员，2007年于西安电子科技大学获得博士学位，主要从事固体、非线性光学及大功率应用等方面的研究。E-mail：zhangshenjin@163.com

中图分类号:TN244
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出版历程
- 收稿日期:2021-11-08
- 录用日期:2022-01-24
- 修回日期:2021-11-18
- 网络出版日期:2022-04-27

The principle, performance characterization and research progress of nonlinear optical limiting materials

LV Ze^{1, 4,},
FANG You^{1, 4},
FENG Tiao^{3, 4},
ZONG Nan^{1, 2,,},
LI Yun-fei^3,,,
ZHANG Shen-jin^{1, 2,,},
XIE Zheng³,
PENG Qin-jun^{1, 2}

1.
Key Laboratory oF Solid State Laser, Institute of Physical and Chemical Technology, Chinese Academy of Sciences, Beijing 100190, China
2.
Key Laboratory of Functional Crystal and Laser Technology, Institute of Physical and Chemical Technology, Chinese Academy of Sciences, Beijing 100190, China
3.
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Institute of Physics and Chemistry Technology, Chinese Academy of Sciences, Beijing 100190, China
4.
University of Chinese Academy of Sciences, Beijing 100049, China

Funds:Supported by Major Program of National Natural Science Foundation of China (No. 51890864); Fund of Technical Institute of Physics and Chemistiy, Chinese Academy of Sciences (No. E0A8053H12).

More Information

Corresponding author:zongnan@mail.ipc.ac.cn;liyunfei@mail.ipc.ac.cn;zhangshenjin@163.com

摘要

摘要:
防护材料在保护人眼和光学器件免受强破坏方面具有重要意义，其中基于非线性光学原理工作的固态光限幅材料有望成为未来防护的主体。本文介绍了光限幅材料的研究背景、工作机理、参数指标以及测试技术，综述了目前具有实用前景的多类光限幅材料的研究进展，对无机半导体材料、共轭有机高分子、无机金属团簇、碳纳米材料、二维材料等5类材料做了重点介绍，探讨这些光限幅材料的发展前景，并介绍了相关材料在固态基质中器件化的研究现状。
- 光限幅/
- 非线性光学/
- 防护
Abstract:
Laser protection materials are of great significance in protecting human eyes and optical components from strong laser pulses. Among them, solid optical limiting materials based on the principle of nonlinear optics will be the main carriers for laser protection. This article introduces the research background, working mechanism, parameters and testing techniques of optical limiting materials, and reviews the research progress of various optical limiting materials with practical prospects, including inorganic semiconductor materials, conjugated organic polymers, inorganic metal clusters, carbon nanomaterials, and two-dimensional materials. And the development prospects of optical limiting materials are discussed.
- optical limiting/
- nonlinear optics/
- laser protection

HTML全文

图 1典型的光限幅效应

Figure 1.Typical optical limiting effect

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图 2反饱和吸收机制^[2]

Figure 2.Reverse saturated absorption mechanism^[2]

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图 3双光子吸收机制^[2]

Figure 3.Two-photon absorption mechanism^[2]

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图 4非线性折射原理图^[2]。（a）典型的自散焦光学结构；（b）典型的自聚焦光学结构

Figure 4.Nonlinear refraction schematic diagrams^[2]. (a) Typical self-defocusing optical structure; (b) typical self-focusing optical structure

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图 5光限幅响应曲线图^[4]

Figure 5.The response of an optical limiter^[4]

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图 6Z-扫描系统原理图^[4]

Figure 6.Z-scan system schematic diagram^[4]

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图 7（a）开孔Z-扫描曲线及（b）闭孔Z-扫描曲线

Figure 7.(a) Open hole Z-scan curve and (b) close hole Z-scan curve

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表 15类光限幅材料的限幅机理、性能特点及目前的技术指标

Table 1.The mechanism, characteristics and the technical indicators of the five types of optical limiting materials

材料类别	光限幅机理	性能特点	代表材料	光限幅技术指标	参考文献
无机半导体材料	双光子吸收载流子吸收非线性折射	制备简单、成本低廉、物化性质稳定，限幅波段单一、线性吸收大	CuS	限幅阈值：0.88 J/cm²@532 nm	[15]
			ZnO	限幅阈值：~6 mW@633 nm	[16]
			TiS₂	限幅阈值：0.57 J/cm²	[17]
共轭有机高分子	反饱和吸收	适用于脉宽纳秒量级以上的脉冲、限幅阈值低	J-dimers	限幅阈值：0.03 J/cm²@532 nm	[18]
			(NiNc(COONa)₄/TiO₂)_n	限幅波段：600 nm@18 ps	[19]
			MnPcCl	限幅波段：633 nm，533 nm	[20]
无机金属团簇	非线性折射反饱和吸收	结构多样、线性吸收小、非线性性能强	MoS₄Cu₂	限幅阈值：0.35 J/cm²@532 nm	[21]
碳基纳米材料	反饱和吸收非线性折射非线性散射	限幅阈值低、限幅波段宽，损伤阈值高、适用于纳秒、皮秒脉冲，固态化技术成熟	C₆₀(Toluene)	限幅阈值：0.2 J/cm²@532 nm	[22]
			MWNTS	限幅阈值：1 J/cm²@532 nm	[23]
			GO-Pt-2	限幅阈值：0.85 J/cm²@532 nm	[24]
二维材料	反饱和吸收非线性折射非线性散射	限幅波段宽，可用于飞秒脉冲，物化性质优异	Si−antimonene	限幅波段：532~2000 nm 限幅阈值：0.3~2 J/cm²@532 nm	[25]
二维材料	反饱和吸收非线性折射非线性散射	限幅波段宽，可用于飞秒脉冲，物化性质优异	F₁₆PcGa-BP	限幅波段：415~590 nm 限幅阈值：2.64 J/cm²@532 nm	[26]

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