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增强吸收光谱技术的研究进展及展望

任颐杰,颜昌翔,徐嘉蔚

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任颐杰, 颜昌翔, 徐嘉蔚. 增强吸收光谱技术的研究进展及展望[J]. , 2023, 16(6): 1273-1292. doi: 10.37188/CO.2022-0246
引用本文: 任颐杰, 颜昌翔, 徐嘉蔚. 增强吸收光谱技术的研究进展及展望[J]. , 2023, 16(6): 1273-1292.doi:10.37188/CO.2022-0246
REN Yi-jie, YAN Chang-xiang, XU Jia-wei. Development and prospects of enhanced absorption spectroscopy[J]. Chinese Optics, 2023, 16(6): 1273-1292. doi: 10.37188/CO.2022-0246
Citation: REN Yi-jie, YAN Chang-xiang, XU Jia-wei. Development and prospects of enhanced absorption spectroscopy[J].Chinese Optics, 2023, 16(6): 1273-1292.doi:10.37188/CO.2022-0246

增强吸收光谱技术的研究进展及展望

doi:10.37188/CO.2022-0246
基金项目:国家自然科学基金(No. 61805235,No. 61905241,No.61875192)
详细信息
    作者简介:

    任颐杰(1994—),男,山西长治人,博士,2018年于长春理工大学的获得学士学位,主要从事腔衰荡光谱技术、 光学系统设计方面的研究。E-mail:ryijie@126.com

    颜昌翔 (1973—),男,湖北洪湖人,博士,研究员,1995年于长春光学精密机械学院获得学士学位,1998年于浙江大学获得硕士学位,2001年于中国科学院长春光学精密机械与物理研究所获得博士学位,主要从事空间光学遥感仪器的光机电一体化技术,多光谱、超光谱空间遥感成像技术、偏振探测技术、可调谐半导体 吸收光谱技术、腔衰荡光谱技术等方面的研究。E-mail:yancx0128@126.com

  • 中图分类号:O433.1

Development and prospects of enhanced absorption spectroscopy

Funds:Supported by National Natural Science Foundtion of China (No. 61805235, No. 61905241, No. 61875192)
More Information
  • 摘要:

    光程吸收光谱技术是吸收光谱技术发展中的一个重要分支,近年来基于不同光源技术、吸收腔技术、探测方式的光程吸收光谱技术大量涌现。随着对探测灵敏度和吸收光程长度需求的提高,出现了基于增强吸收原理的光程吸收光谱技术,包括:积分腔光谱(ICOS)、腔增强吸收光谱(CEAS)和腔衰荡光谱(CRDS)。增强吸收光谱技术具有高光谱分辨率、高灵敏度、快速响应、便携等优势,但至今缺乏统一的概念和明确的分类依据。本文梳理了吸收光谱技术的发展历程,明确了多光程吸收光谱技术的概念。依据吸收腔内是否发生谐振吸收,提出了基于谐振原理的吸收光谱技术这一概念,分析总结了谐振吸收光谱技术的研究现状,并对这些技术在各领域的应用进行概述。最后,对谐振吸收光谱技术中关键技术的未来发展进行了展望。

  • 图 1转化吸收光谱技术原理图。(a) 诱导荧光技术;(b)共振增强多光子电离技术;(c)光声光谱技术

    Figure 1.Schematic diagram of conversion absorption spectroscopy technology. (a) Laser induced fluorescence-(LIF); (b) resonance enhanced multiphoton ionization-(REMPI); (c) photoacoustic spectroscopy (PAS)

    图 2光程吸收光谱技术与转化吸收光谱技术的分类图

    Figure 2.Classification of optical path absorption spectroscopy and conversion absorption spectroscopy

    图 3不同光程吸收光谱技术的吸收光程长度。非分散红外(NDIR)、差分吸收光谱(DOAS)、可调谐半导体 吸收光谱(TDLAS)、积分腔光谱(ICOS )、离轴积分腔输出光谱(OA-ICOS)、宽带腔增强吸收光谱(BB-CEAS)、离轴腔增强吸收光谱(OF-CEAS)、腔衰荡光谱(CRDS)

    Figure 3.Absorption optical paths length in different optical path absorption spectroscopy technologies: non-dispersive (NDIR), differential optical absorption spectroscopy (DOAS), tunable diode laser absorption spectroscopy (TDLAS), integrated cavity output spectroscopy (ICOS), off-axis ICOS (OA-ICOS), broadband cavity-enhanced absorption spectroscopy (BB-CEAS), optical feedback CEAS (OF-CEAS), and cavity ring-down spectroscopy (CRDS)

    图 4(a)直接吸收TDLAS技术原理图;(b)多通池TDLAS技术的实验装置图[16]

    Figure 4.(a) Schematic diagram of direct absorption TDLAS technology; (b) experimental setup diagram of multi-channel absorption cell TDLAS technology[16]

    图 5(a)主动(b)被动差分吸收光谱技术示意图

    Figure 5.Schematic diagram of (a) active and (b) passive differential optical absorption spectroscopy

    图 6(a)White腔原理图[32]。平面光学多通池的(b)三维结构图及(c)仿真模型[34]

    Figure 6.(a) Schematic diagram of White cavity[32]. (b) Three-dimensional structure diagram of the planar optical multipass cell and (c) its simulation model[34]

    图 7波长调制离轴积分腔光谱测量系统原理图[35]

    Figure 7.Schematic diagram of wavelength modulation in the off-axis integral cavity output spectroscopy[35]

    图 8宽谱腔增强吸收光谱技术装置示意图

    Figure 8.Schematic diagram of the broadband cavity-enhanced absorption spectroscopy device

    图 9离轴入射腔增强吸收光谱技术原理图

    Figure 9.Schematic diagram of OA-CEAS technology

    图 10光反馈腔增强吸收光谱技术原理图

    Figure 10.Schematic diagram of optical feedback cavity enhanced absorption spectroscopy

    图 11衰荡光谱技术的测量原理图

    Figure 11.Schematic diagram of measurement principle of the decay absorption spectroscopy technique

    图 12(a)三角腔横模匹配示意图;(b)纵模匹配示意图

    Figure 12.(a) Schematic diagram of triangular cavity transverse mode matching; (b) schematic diagram of longitudinal mode matching

    图 13线性腔腔衰荡光谱技术的测量原理图

    Figure 13.Measurement diagram of linear cavity ring-down spectroscopy

    图 14环形腔衰荡光谱技术测量原理图。(a)三角腔;(b)蝶形腔

    Figure 14.Measurement diagrams of cavity ring-down spectroscopy with (a) triangular cavity and (b) butterfly cavity

    图 15光纤环形腔衰荡光谱技术原理图

    Figure 15.Schematic diagram of fiber loop ring-down spectroscopy

    图 16三角腔中基于Hermite-Gaussian模激发特性的高精度对准方案[120]

    Figure 16.High-precision alignment scheme based on Hermite-Gaussian mode excitation characteristics in a triangular cavity[120]

    图 17三角腔中Hermite-Gaussian模耦合的实验装置图[121]

    Figure 17.Structural diagram of the triangular cavity Hermite-Gaussian mode resonance coupling experimental setup[121]

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  • 收稿日期:2022-11-28
  • 修回日期:2023-01-03
  • 网络出版日期:2023-04-17

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