Synthesis and luminescence properties of La1.6(MoO4)3:Eu0.43+nanocrystal
-
摘要:采用燃烧法合成了La1.6(MoO4)3:Eu0.43+纳米晶末,研究了其声子-掺杂-晶格相互作用和发光性质.X射线粉末衍射(XRD)分析表明,在500~900 ℃退火后,La1.6(MoO4)3:Eu0.43+样品为单一晶相.对样品进行了光致发光(PL)测量,激发Mo6+-O2-电荷迁移带,观察到Eu3+的系列发光,表明Mo6+-O2-带和Eu3+间存在能量传递,中心波长分别在1=469 nm和2=426 nm处的两个one-phonon边带,相应的声子能量分别为767和1202 cm-1,分别对应于 Mo=O 和MoOMo伸缩振动.同时,计算了两个局域模电子-声子耦合强度的黄昆因子分别为S1=0.055和S2=0.037,为揭示其三价离子高传导特性及其负热膨胀物理特性提供了实验基础.
-
关键词:
- 发光特性/
- 燃烧法/
- La1.6(MoO4)3:Eu0.43+纳米晶/
- 局域模/
- one-phonon 边带
Abstract:La1.6(MoO4)3:Eu0.43+ nancrystal is synthesized by combustion method and the interaction between the phonon-dopant-lattice and luminescence properties of this nanocrystal are investigated. It is shown by X-ray diffraction that the powders are crystallized in a single phase annealed at 500~900 ℃. It is found that the excitation of the Mo6+-O2- charge transfer band(CTB) can result in the emissions of Eu3+ ion, which indicates that energy transfer takes place from CTB to Eu3+ ions. Two one-phonon sidebands locate at 1=469 nm and 2=426 nm in the excitation spectra which are due to Mo=O and MoOMo expand and contract vibration modes, respectively, with phonon energies of 1 202 cm-1 and 767 cm-1. The Huang-Kun factors S1=0.055 and S2=0.037 describing the interaction intensity between phonon and lattice are determined. The optical properties of La1.6(MoO4)3:Eu0.43+ would be able to provide the experimental foundation to reveal the properties of high conductivity and negative thermal expansion(NTE) with the trivalent ions. -
[1] IMANAKA N,TAMURA S,ADACHI G,et al.. Electronic state of trivalent ionic conductors with Sc2(WO4)3-type structure[J].Solid State Ionics,2000,130(3-4):179-182.
[2] NEERAJ S,KIJIMA N,CHEETHAM A K. Novel red phosphors for solid-state lighting:the system NaM(WO4)2-x(MoO4)x:Eu3+(M=Gd,Y,Bi)[J].Chem. Phys. Lett.,2004,387(1):2-6.
[3] SHA R,GAO W,LIU Y P. Luminescence properties of Na0.35Ba Mo8O16:Eu3+phosphor for white LED[J].J. Chinese Lumin.,2013,34(11):1469-1473.
[4] GENG X Z,TIAN Y W,CHEN Y J,et al.. Hydrothermal syntheses and spectral properties of MMoO4:Eu3+(M=Ca,Sr,Ba) red phosphors[J].J. Chinese Lumin.,2011,32(7):670-674.
[5] LIU X R. Phosphors for white LED solid state lighting[J].J. Chinese Lumin.,2007,28(3):291-301.
[6] IMANAKA N,KOBAYASHI Y,TAMURA S,et al.. Trivalent Al3+ion conduction in Al2(WO4)3solids[J].Electrochem. Solid-State Lett.,1998,1(6):2713.
[7] IMANAKA N,TAMURA S,KOBAYASHI Y,et al.. Trivalent rare earth ion conduction in the scandium tungstate type structure[J].J. Alloys Compds.,2000,303/304:303-306.
[8] OKAZAKI Y,UEDA T,TAMURA S,et al.. Trivalent Sc3+ion conduction in the Sc2(WO4)3Sc2(MoO4)3solid solution[J].Solid State Ionics,2000,136/137:437440.
[9] LIU H,SECCO R A,IMANAKA N,et al.. Ionic to electronic dominant conductivity in Al2(WO4)3at high pressure and high temperature[J].J. Phys. Chem. Solids,2003,64(2):287-294.
[10] XUE J S,ANTONIO M R,SODERHOLM L. Polymorphs of Ln2MoO6:a neutron diffraction investigation of the crystal structures of La2MoO6and Tb2MoO6[J].Chem. Mater.,1995,7(2):333-340.
[11] BLASSE G. On the Eu3+fluorescence in mixed metal oxides.V.the Eu3+fluorescence in the rocksalt lattice[J].J. Chem. Phys.,1966,45(6):3327-3331.
[12] LIU CH X,LIU J Y. Judd-Ofelt intensity parameters and spectral properties of Gd2O3:Eu3+nanocrystals[J].J. Phys. Chem. B,2006,110(41):20277-20281.
[13] PANG M,LIU X,LIN J. Luminescence properties of R2MoO6:Eu3+(R=Gd,Y,La) phosphors prepared by Pechini sol-gel process[J].J. Mater. Res.,2005,20(10):2676-2681.
[14] HUANG J,LORIERS J,PORCHER P. Spectroscopic properties of Ln2MoO6:Eu3+[J].J. Solid State Chem.,1982,43(1):87-96. -
点击查看大图
计量
- 文章访问数:1110
- HTML全文浏览量:214
- PDF下载量:791
- 被引次数:0
下载:
