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摘要:钙钛矿材料不仅具有载流子扩散长度长、可调节带隙宽、光吸收效率大等优点，并且其原料储量十分丰富，沉积过程所需的形成能较低，制备工艺可兼容大面积制造技术。总之，低生产成本、高转换效率和宽应用领域等优点使钙钛矿太阳能电池可与硅基太阳能电池相媲美，在能源生产中优势十分明显。在现阶段的钙钛矿研究中，高稳定性和大制备面积是钙钛矿光伏技术的研究热点，也是亟待突破的难点。本文综述了近年来采用印刷技术制备钙钛矿太阳能电池的原料组成、工艺控制等方面的研究进展，简述并比较了各种印刷技术的优点与局限性。重点讨论了钙钛矿太阳能电池印刷制备时需要考虑的因素，并列举了对于改善钙钛矿太阳能电池薄膜性能不同制备方法的尝试，评价了对于提高器件稳定性及工业生产适用性所采取的一些策略。Abstract:Perovskite materials have the advantages of long carrier diffusion length, tunable band gap and high light absorption efficiency. Additionally, the storage of raw materials used in the production of perovskite solar cells is very rich and the formation energy required for the deposition process is low. Meanwhile, the production process is compatible with large-area manufacturing techniques. Low production cost, high conversion efficiency and wide application fields make the perovskite solar cells comparable to silicon-based solar cells. In today's perovskite research, high stability and large-area production are the research hotspots of photovoltaic technology. The research progress of the ink composition and process control of recent printing techniques are reviewed in this paper. The advantages and limitations of these methods are briefly described and compared. We focus on the factors that need to be considered in the production of perovskite solar cells, different preparation methods that can improve perovskite film quality and strategies for improving stability and applicability in industrial production.
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Key words:
- perovskites/
- solar cells/
- printing technique
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