稀土掺杂材料的上转换发光 -

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稀土掺杂材料的上转换发光

1.
长春职业技术学院,吉林长春 130033;
2.
大连海事大学物理系,辽宁大连 116026

基金项目:

国家自然科学基金资助项目(No.50972021);国家民航总局联合基金资助项目(No.60776814);辽宁省自然科学基金资助项目(No.20082139)

详细信息

作者简介:

花景田(1970—),男,吉林九台人,副教授,主要从事光电信息科学技术领域的研究。 E-mail:huajingtian@shoo.com
陈宝玖(1970—),男,辽宁阜新人,教授,博士生导师,主要从事稀土发光材料制备及光谱学性质方面的研究。E-mail:chenmbj@sohu.com

花景田(1970—),男,吉林九台人,副教授,主要从事光电信息科学技术领域的研究。 E-mail:huajingtian@shoo.com
陈宝玖(1970—),男,辽宁阜新人,教授,博士生导师,主要从事稀土发光材料制备及光谱学性质方面的研究。E-mail:chenmbj@sohu.com

中图分类号:O482.31
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出版历程
- 收稿日期:2010-03-11
- 修回日期:2010-05-13
- 刊出日期:2010-08-25

Introduction to up-conversion luminescence of rare earth doped materials

1.
Changchun Vocational Institute of Technology,Changchun 130033,China;
2.
Department of Physics,Dalian Maritime University,Dalian 116026,China

摘要

摘要:稀土掺杂材料的上转换发光是实现光波频率转换的重要途径,也是稀土掺杂发光材料研究的重要内容。本文从介绍与上转换相关的基本概念出发,阐述了稀土离子上转换发光的发展历史;对稀土离子掺杂材料的能量传递、激发态吸收、合作敏化、合作发光、双光子吸收激发及光子吸收雪崩等上转换发光机制进行了概述,并对各机制进行了比较;对不同稀土离子掺杂体系中上转换发光的机制进行了总结;对以往研究的稀土掺杂上转换发光材料的基质,包括粉体材料、晶体材料、非晶材料进行了概括;最后对影响稀土离子上转换发光效率的因素进行了分析,提出了在上转换发光材料的设计中应重点考虑基质对泵浦光及上转换发射光的吸收、基质材料的声子能量、稀土离子的掺杂方案及泵浦途径等因素。
- 上转换发光/
- 稀土离子/
- 基质材料/
- 掺杂发光/
- 发光效率
Abstract:Up-conversion luminescence in rare earth doped materials is an important approach for the optical frequency conversion as well an important aspect in the researches of luminescent materials. On the basis of the introduction of fundamental concepts of the up-conversion luminescence, the research history of up-conversion luminescence of rare earth doped materials was briefly reviewed and the up-conversion mechanisms including energy transfer, excited state absorption, co-operative sensitization, co-operative luminescence, two-photon absorbed excitation and photon avalanche processes in rare earth doped materials were summarized and compared with each others. Then, the up-conversion luminescence mechanisms for various rare earths doped materials were summarized and the host materials such as phosphors, crystal and non-crystalline solids for rare earth were introduced. Finally, the factors influencing the up-conversion luminescence efficiency were analyzed. It was pointed out that the absorptions of pumping light and emitting light, phonon energies of host materials, the choices of doping ions and pumping routes must be considered in the designs of up-conversion luminescence materials.
- up-conversion luminescence/
- rare earth ion/
- host matrix/
- doping luminescence/
- luminescence efficiency

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参考文献 (1)

[1] 陈宝玖. 稀土离子掺杂的玻璃材料制备及上转换发光 . 长春:中国科学院长春光学精密机械与物理研究所 ,1999. CHEN B J. Preparation and upconversion luminescence of rare earth doped glasses .Changchun:Changchun Institute of Optics,Fine Mechanics and Physics,Chinese Academy of Sciences,1999.(in Chinese)

[2] 孟庆裕. 纳米颗粒表面效应和尺寸限制对稀土离子发光的影响 . 长春:中国科学院长春光学精密机械与物理研究所 ,2007. MENG Q Y. Effects of surface and size-confinement on the rare earth luminescence .Changchun:Changchun Institute of Optics,Fine Mechanics and Physics,Chinese Academy of Sciences,2007.(in Chinese)

[3] 王博. 三价铒离子在ZBLAN中光学跃迁的研究 . 大连:大连海事大学 ,2008. WANG B. Optical transitions of trivalent erbium in ZBLAN .Dalian:Dalian Maritime University,2008.(in Chinese)

[4] 徐东勇,臧竞存. 上转换和上转换发光材料的研究进展
[J]. 人工晶体学报 ,2001,30(2):203-210. XU D Y,ZANG J C. Progress of study on upconversion laser & luminescence materials
[J].J. Synthetic Cryst.,2001,30(2):203-210.(in Chinese)

[5] 陈晓波,张光寅,宋增福. 稀土化合物材料上转换发光与的研究与进展
[J]. 光谱学与光谱分析 ,1995,15(3):1-6. CHEN X B,ZHANG G Y. SONG Z F. Progress in upconversion laser and luminescence of rare earths doped compounds
[J].Spectroscopy Spec. Anal.,1995,15(3):1-6. (in Chinese)

[6] 杨建虎,戴世勋,姜中宏. 稀土离子的上转换发光及研究进展
[J]. 物理学进展 ,2003,23(3):284-298. YANG J H,DAI SH X,JIANG ZH H. Upconversion emission of rare earth ions and its recent developments
[J].Prog. Phys.,2003,23(3):284-298.(in Chinese)

[7] LIU M,WANG S W,ZHANG J,et al.. Upconversion luminescence of Y₃Al₅O₁₂(YAG)∶ Yb³⁺,Tm³⁺nanocrystals
[J].Opt. Mater.,2007,30(7):370-374.

[8] GOUVEIA-NETO A S,BUENO L A,AFONSO A C M,et al.. Upconversion Luminescence in Ho³⁺/Yb³⁺and Tb³⁺/Yb³⁺codoped fluorogermanate glass and glass ceramic
[J].J. Non-Cryst. Solids,2008,354(10):509-514.

[9] IPARRAGUIRRE I,AZKARGORTA J,FERNANDEZ-NAVARRO J M,et al.. Laser action and upconversion of Nd³⁺in tellurite bulk glass
[J].J. Non-Cryst. Solids,2007,353(2):990-992.

[10] ZHANG X D,XU T F,DAI S X,et al.. Investigation of energy transfer and frequency upconversion in Er³⁺/Ho³⁺co-doped tellurite glasses
[J].J. Alloy. Compd.,2008,450(10):306-309.

[11] 陈宝玖,王海宇,秦伟平,等. Yb³⁺和Er³⁺共掺杂氟硼酸盐玻璃材料光学跃迁及红外到可见上转换
[J]. 发光学报 ,2000,21(1):38-42. CHEN B J,WANG H Y,QIN W P,et al.. Optical transitions and IR to visible upconversion of Yb³⁺and Er³⁺co-doped fluoroborate glass
[J].Chin. J. Lumin.,2000,21(1):38-42.(in Chinese)

[12] 陈宝玖,王海宇,秦伟平,等. 高效的红外到可见上转换氟氧化物玻璃材料
[J]. 光谱学与光谱分析 ,2000,20(3):257-259. CHEN B J,WANG H Y,QIN W P,et al.. Oxyfluoride glass for high efficient upconversion from IR to green
[J].Spectroscopy Spectral Anal.,2000,20(3):257-259.(in Chinese)

[13] 杨艳民. 稀土离子掺杂透明无机绝缘体材料红外光谱性质的研究 . 长春:中国科学院长春光学精密机械与物理研究所 ,2007. YANG Y M. Investigation of infrared spectroscopic properties in rare earth ions doped insulating inorganic materials .Changchun:Changchun Institute of Optics,Fine Mechanics and Physics,Chinese Academy of Sciences,2007.(in Chinese)

[14] LIU M,WANG S W,ZHANG J,et al.. Dominant red emission (⁴F_9/2-⁴I_15/2) via upconversion in YAG(Y₃Al₅O₁₂)∶Yb³⁺,Er³⁺nanopowders
[J].Opt. Mater.,2007,29(3):1352-1357.

[15] DUAN Z C,ZHANG J J,XIANG W D,et al.. Multicolor upconversion of Er³⁺/Tm³⁺/Yb³⁺doped oxyfluoride glass ceramics
[J].Mater. Lett.,2007,61(9):2200-2203.

[16] NICOLAS S,DESCROIX E,JOUBERT M F,et al.. Potentiality of Pr³⁺and Pr³⁺/Ce³⁺doped crystals for tunable UV upconversion lasers
[J].Opt. Mater.,2003,22(2):139-146.

[17] GERNER P,FUHRER C,REINHARD C,et al.. Near infrared to visible photon upconversion in Mn²⁺and Yb³⁺containing materials
[J].J. Alloys Compd.,2004,380(1):39-44.

[18] MARTIN I R,GOUTAUDIER C,GUY S,et al.. Room-temperature photon avalanche upconversion in Tm³⁺∶ Y₂O₃crystals
[J].Phys. Rev. B,1999,60(10):7252-7257.

[19] LOZANO W B,ARAUJO C B,MESSADDEQ Y,et al.. Enhanced frequency upconversion in Er³⁺doped fluoroindate glass due to energy transfer from Tm³⁺
[J].J. Non-Cryst. Solids,2002,11(7):318-322.

[20] GIRI N K,RAI D K,RAI S B. White light upconversion emissions from Tm³⁺+Ho³⁺+Yb³⁺codoped tellurite and germanate glasses on excitation with 798 nm radiation
[J].J. Appl. Phys.,2008,104(12):113107/1-113107/5.

[21] GIRI N K,SINGH A K,RAI S B. Efficient blue upconversion emission in Tm³⁺via energy transfer from Yb³⁺doped in lithium modified tellurite glass
[J].J. Appl. Phys.,2007,101(2):033102/1-033102/4.

[22] QUIMBY R S,CONDON N J,OCONNOR S P,et al.. Upconversion and excited-state absorption in the lower levels of Er∶ KPb₂Cl₅
[J].Opt. Mater.,2008,30(3):827-834.

[23] BOUFFARD M,DUVAUT T,JOUART J P,et al.. Site-selective upconversion excitation of Er³⁺∶ KYF₄
[J].J. Phys.:Condens. Mater.,1999,11(3):4775-4782.

[24] RAKOV N,ARAUJO C B,MESSADDEQ Y,et al.. Avalanche upconversion in Er³⁺doped fluoroindate glass
[J].Appl. Phys. Lett.,1997,70(23):3084-3086.

[25] KNOWLES D S,JENSSEN H P. Upconversion versus Pr-deactivation for efficient 3 μm laser operation in Er
[J].IEEE J. Quat. Electron.,1992,28(4):1197-1208.

[26] ZHONG H Y,CHEN B J,REN G Z,et al.. 2.7 μm emission of Nd³⁺,Er³⁺codoped tellurite glass
[J].J. Appl. Phys.,2009,106(1) in press.

[27] WANG D Y,LUO J L,CHAO X B,et al.. Upconversion fluorescence in LiKGdF₅single crystal co-doped with Er³⁺,Tb³⁺
[J].SPIE,2006,6028:602807/1-602807/5.

[28] WANG D Y,LUO J L,LIU J Q,et al.. Energy transfer upconversion in Er³⁺doped and Er³⁺,Ho³⁺codoped Cs₂NaGdCl₆crystals
[J].SPIE,2005,6028:60280S/1-60280S/5.

[29] LAHOZ F,MARTIN I R,BRIONES A. Infrared-laser induced photon avalanche upconversion in Ho³⁺-Yb³⁺codoped fluoroindate glasses
[J].J. Appl. Phys.,2004,95(6):2957-2962.

[30] W ANG X Y,LIN H,YANG D L,et al.. Optical transitions and upconversion fluorescence in Ho³⁺/Yb³⁺doped bismuth tellurite glasses
[J].J. Appl. Phys.,2007,101(6):113535/1-113535/5.

[31] YANG H G,DAI Z W, LI J F,et al.. Energy transfer and frequency upconversion in Pr³⁺-doped ZBLAN glass
[J].J. Non-Cryst. Solids,2006,352(9):5469-5474.

[32] GOMES A S L,MACIEL G S,ARAUJO R E,et al.. Diode pumped avalanche upconversion in Pr³⁺doped fibers
[J].Opt. Commun.,1993,103(5-6):361-364.

[33] EDISON F F L,ARAUJO C B,MESSADDEQ Y. Frequency upconversion involving triads and quartets of ions in a Pr³⁺/Nd³⁺codoped fluoroindate glass
[J].J. Appl. Phys.,2001,92(6):3065-3070.

[34] BANEY D M,RANKIN G,CHANG K W. Simultaneous blue and green upconversion lasing in a laser-diode-pumped Pr³⁺/Yb³⁺doped fluoride fiber laser
[J].Appl. Phys. Lett.,1996,69(12):1662-1664.

[35] IPARRAGUIRRE I,AZKARGORTA J,FERNANDEZ-NAVARRO J M,et al.. Laser action and upconversion of Nd³⁺in tellurite bulk glass
[J].J. Non-Crystal. Solids,353(2):990-992.

[36] QIU J. Energy transfer process and Tb³⁺up-conversion luminescence in Nd³⁺/Yb³⁺/Tb³⁺co-doped fluorozirconate glasses
[J].J. Lumin.,2000,86(1):23-31.

[37] QIU J,SHOJIYA M,KANNO R,et al.. Selectively strong green up-conversion luminescence in Nd³⁺-Ho³⁺co-doped ZrF₄based fluoride glasses under 800 nm excitation
[J].J. Phys.:Condens. Matter.,1998,10(12):11095-11102.

[38] WANG X F,BU Y Y,XIAO S G,et al.. Novel upconversion phenomenon of Nd³⁺sensitized by Yb³⁺in Nd³⁺-Yb³⁺codoped a-Na(Y_1.5Na_0.5)F₆
[J].Mater. Lett.,2008,62(23):3865-3867.

[39] MA H P,ZHU B G,ZOU F L,et al..Three-photon-excited fluorescence of Tb³⁺-doped CaO-Al₂O₃-SiO₂glass by femtosecond laser irradiation
[J].J. Rare Earths,2008,26(6):928-931.

[40] NOGINOV M A,VENKATESWARLU P,MAHADI M. Two-step upconversion luminescence in Yb∶ Tb∶ YSGG Crystals
[J].J. Opt. Soc. Am. B,1996,13(2):735-741.

[41] KACZKAN M,FRUKACZ Z,MALINOWSKI M. Infrared to visible wavelength upconversion in Sm³⁺activated YAG crystals
[J].J. Alloys Compd.,2001,323-324:736-739.

[42] LAVIN V,LAHOZ F,MARTIN I R,et al.. Infrared-to-visible photon avalanche upconversion dynamics in Ho³⁺doped fluorozirconate glasses at room temperature
[J].Opt. Mater.,2005,27(12):1754-1761.

[43] KUMAR G A,MARTINEZ A,MEJIA E. Fluorescence and upconversion spectral studies of Ho³⁺in alkali bismuth gallage glasses
[J].J. Alloys Compd.,2004,365(1):117-120.

[44] LAHOZ F,MARTIN I R,BRIONES A. Infrared laser induced photon avalanche upconversion in Ho³⁺-Yb³⁺codoped fluoroindate glasses
[J].J. Appl. Phys.,2004,95(6):2957-2962.

[45] YANG L M,SONG H W,YU L X,et al.. Unusual power-dependent and time-dependent upconversion luminescence in nanocrystals Y₂O₃∶ Ho³⁺/Yb³⁺
[J].J. Lumin.,2006,116(1):101-106.

[46] VALIENTE R,WENGER O S,GUDEL H U. Upconversion luminescence in Yb³⁺doped CsMnCl₃:Spectroscopy, dynamics, and mechanisms
[J].J. Chem. Phys.,2002,116(12):5196-5204.

[47] QIN G S,QIN W P,HUANG S H. Up-converting Yb³⁺-Er³⁺co-doped amorphous fluoride thin films prepared by pulsed-laser deposition for visible light source
[J].Solid State Commun.,2001,120(2):211-214.

[48] XU S Q,ZHANG J J,DAI S X,et al.. Host dependent frequency upconversion of Er³⁺doped oxyfluoride tellurite glasses
[J].J. Alloys Compd.,2004,376(11):L1-L4.

[49] LIU G K,JACQUIER B.Spectroscopic Properties of Rare Earths in Optical Materials
[M]. Tsinghua University Press,Springer Press,2005:277.