Volume 14Issue 3
May 2021
Turn off MathJax
Article Contents
ZHAO Hai-qin, WANG Lin-xiang, TUO Juan, YE Ying. Luminescence properties of Bi3+ doped Lu1-xO3: x%Ho3+ metal ion phosphors[J]. Chinese Optics, 2021, 14(3): 528-535. doi: 10.37188/CO.2019-0222
Citation: ZHAO Hai-qin, WANG Lin-xiang, TUO Juan, YE Ying. Luminescence properties of Bi3+doped Lu1-xO3:x%Ho3+metal ion phosphors[J].Chinese Optics, 2021, 14(3): 528-535.doi:10.37188/CO.2019-0222

Luminescence properties of Bi3+doped Lu1-xO3:x%Ho3+metal ion phosphors

doi:10.37188/CO.2019-0222
Funds:Supported by Natural Science Foundation of Xinjiang (No. 2017D01A60); Scientific Research Plan of Colleges and University in Xinjiang (No. XJEDU2018Y032)
More Information
  • Corresponding author:wanglinxiang23@126. com
  • Received Date:26 Nov 2019
  • Rev Recd Date:21 Jan 2020
  • Available Online:17 Apr 2021
  • Publish Date:14 May 2021
  • Bi 3+doped Lu 1-xO 3: x%Ho 3+metal ion phosphors were prepared using the high-temperature solid-phase method. The crystal structures of Bi 3+doped Lu 1-xO 3: x%Ho 3+phosphors, the Bi 3+→Ho 3+energy transfer rule in Lu 2O 3matrix and the luminescent properties of synthetic powders with different doping concentrations were investigated. X-ray diffraction results showed that Bi 3+and Ho 3+doping had no effect on the cubic phase structure of Lu 2O 3. Lu 2O 3: Ho 3+, Bi 3+phosphor emitted 5S 25I 8transition of Ho 3+at 551 nm under an excitation wavelength of 322 nm, and exhibited 1S 03P 1characteristic transition of Bi 3+at 322 nm and 5I 85F 1transition of Ho 3+at 448 nm under an emission wavelength of 551 nm. When the doping concentration of Bi 3+was 1.5%, the effect was most effective for the energy transfer of Ho 3+, which increased by a factor of 34.8 compared to that of the single-doped Ho 3+sample. For Lu 98.5%−yO 3:1.5%Ho 3+, y%Bi 3+( y=1, 1.5, 2), with the increase of Bi 3+ions concentration, the luminescence intensity at 551 nm under 980-nm excitation increased by a factor of 13.3, 16.8 and 14.2, respectively, compared to that of under 322-nm excitation. The energy transfer critical distance between Bi 3+and Ho 3+was calculated to be 2.979 nm, and the energy transfer between Bi 3+and Ho 3+was achieved by dipole-quadrupole interaction.

  • loading
  • [1]
    贾玉涛. 稀土离子Ho 3+掺杂氧化物上转换光致发光的研究[D]. 苏州: 苏州大学, 2010.

    JIA Y T. Study on up-conversion photo luminescence of rare earth ions Ho 3+doped oxides[D]. Suzhou: Soochow University, 2010. (in Chinese)
    [2]
    FENG L, WU Y S. Optical transitions of Ho 3+in oxyfluoride glasses and upconversion luminescence of Ho 3+/Yb 3+-codoped oxyfluoride glasses[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2015, 142: 232-238. doi:10.1016/j.saa.2015.01.066
    [3]
    BHARGAVI K, RAO M S, SUDARSAN V, et al. Influence of Al 3+ions on self up-conversion in Ho 3+doped lead silicate glasses[J]. Optical Materials, 2014, 36(7): 1189-1196. doi:10.1016/j.optmat.2014.02.027
    [4]
    SURESH B, ZHYDACHEVSKII Y, BRIK M G, et al. Amplification of green emission of Ho 3+ions in lead silicate glasses by sensitizing with Bi 3+ions[J]. Journal of Alloys and Compounds, 2016, 683: 114-122. doi:10.1016/j.jallcom.2016.05.056
    [5]
    李新跃, 邓建国, 刘东亮. 氧化物掺杂稀土的上转换材料研究进展[J]. 信阳师范学院学报: 自然科学版,2011,24(3):414-420.

    LI X Y, DENG J G, LIU D L. Research progress of upconversion materials of oxide matrix with doped rare earths[J]. Journal of Xinyang Normal University: Natural Science Edition, 2011, 24(3): 414-420. (in Chinese)
    [6]
    李佳钰. Bi 3+和几种稀土离子掺杂新型发光材料的合成及性质研究[D]. 沈阳: 沈阳师范大学, 2018.

    LI J Y. Study of the synthesis and luminescent properties of Bi 3+and several rare earth ions doped new optical materials[D]. Shenyang: Shenyang Normal University, 2018. (in Chinese).
    [7]
    郭如旺, 郭常新. Lu 2O 3: Bi 3+粉末晶体发光性能的研究[J]. 中国稀土学报,2007,25(5):533-539. doi:10.3321/j.issn:1000-4343.2007.05.003

    GUO R W, GUO CH X. Luminescent properties of nano- and submicron-crystal Lu 2O 3: Bi 3+[J]. Journal of the Chinese Rare Earth Society, 2007, 25(5): 533-539. (in Chinese) doi:10.3321/j.issn:1000-4343.2007.05.003
    [8]
    RAO T K V, KAMAL C S, SAMUEL T, et al. Color tunable luminescence from LaAlO 3: Bi 3+, Ho 3+doped phosphors for field emission displays[J]. Journal of Materials Science: Materials in Electronics, 2017, 29(2): 1011-1017.
    [9]
    XUE J P, WANG X F, JEONG J H, et al. Spectral and energy transfer in Bi 3+–Re n+( n= 2, 3, 4) co-doped phosphors: extended optical applications[J]. Physical Chemistry Chemical Physics, 2018, 20(17): 11516-11541. doi:10.1039/C8CP00433A
    [10]
    ZENG L W, LIU Y, LIN B H, et al. Rational design of Bi 3+/Ln 3+: GdVO 4(Ln=Eu, Sm, Dy, Ho) nanophosphor: synthesis, characterization and color-tunable property[J]. Optical Materials, 2018, 77: 204-210. doi:10.1016/j.optmat.2018.01.040
    [11]
    赵海琴, 王林香, 庹娟, 等. Li +/Bi 3+掺杂Lu 2O 3: Ho 3+荧光粉的制备及其发光特性[J]. 与光电子学进展,2018,55(8):081602.

    ZHAO H Q, WANG L X, TUO J, et al. Preparation and luminescent properties of Li +/Bi 3+co-doped Lu 2O 3: Ho 3+phosphors[J]. Laser& Optoelectronics Progress, 2018, 55(8): 081602. (in Chinese)
    [12]
    肖全兰, 孟建新, 谢丽娟, 等. Bi 3+掺杂对YVO 4: Yb 3+近红外发光的敏化作用[J]. 物理化学学报,2011,27(10):2427-2431. doi:10.3866/PKU.WHXB20110928

    XIAO Q L, MENG J X, XIE L J, et al. Near-infrared luminescence enhancement by co-doped Bi 3+in YVO 4: Yb 3+[J]. Acta Physico-Chimica Sinica, 2011, 27(10): 2427-2431. (in Chinese) doi:10.3866/PKU.WHXB20110928
    [13]
    KHAN W, ZHOU L LIANG, et al. Luminescence enhancement and energy transfers of Ce 3+and Sm 3+in CaSrSiO 4phosphor[J]. Journal of Materials Chemistry C, 2018, 6(28): 7612-7618. doi:10.1039/C8TC02143K
    [14]
    TAO ZH X, TSUBOI T, HUANG Y L, et al. Photoluminescence properties of Eu 3+-doped glaserite-type orthovanadates CsK 2Gd[VO 4] 2[J]. Inorganic Chemistry, 2014, 53(8): 4161-4168. doi:10.1021/ic500208h
    [15]
    XIA ZH G, MIAO SH H, CHEN M Y, et al. Structure, crystallographic sites, and tunable luminescence properties of Eu 2+and Ce 3+/Li +-activated Ca 1.65Sr 0.35SiO 4phosphors[J]. Inorganic Chemistry, 2015, 54(16): 7684-7691. doi:10.1021/acs.inorgchem.5b00455
    [16]
    GUO Q, WANG Q, JIANG L, et al. A novel apatite, Lu 5(SiO 4) 3N: (Ce, Tb), phosphor material: synthesis, structure and applications for NUV-LEDs[J]. Physical Chemistry Chemical Physics, 2016, 18(23): 15545-15554. doi:10.1039/C6CP01512C
    [17]
    胡莲莲, 艾尔肯·斯地克, 万英, 等. Dy 3+、Tm 3+共掺杂Ca 2MgSi 2O 7的发光特性[J]. 发光学报,2018,39(7):948-954. doi:10.3788/fgxb20183907.0948

    HU L L, AIERKEN S, WAN Y, et al. Luminescent properties of Dy 3+, Tm 3+co-doped Ca 2MgSi 2O 7[J]. Chinese Journal of Luminescence, 2018, 39(7): 948-954. (in Chinese) doi:10.3788/fgxb20183907.0948
    [18]
    DEXTER D L, SCHULMAN J H. Theory of concentration quenching in inorganic phosphors[J]. Journal of Chemical Physics, 1954, 22(6): 1063-1070. doi:10.1063/1.1740265
    [19]
    ZHOU H P, JIN Y, JIANG M S, et al. A single-phased tunable emission phosphor MgY 2Si 3O 10: Eu 3+, Bi 3+with efficient energy transfer for white LEDs[J]. Dalton Transactions, 2015, 44(3): 1102-1109. doi:10.1039/C4DT02114B
    [20]
    杨国辉, 陈凯, 王小军, 等. 基质组成变化及电荷补偿对Na M 4(VO 4) 3: Eu 3+( M=Mg, Ca)荧光性能的调控[J]. 发光学报,2019,40(6):725-734. doi:10.3788/fgxb20194006.0725

    YANG G H, CHEN K, WANG X J, et al. Controlling emissions of Na M 4(VO 4) 3: Eu 3+( M=Mg, Ca) phosphor by adjusting base composition and charge compensation[J]. Chinese Journal of Luminescence, 2019, 40(6): 725-734. (in Chinese) doi:10.3788/fgxb20194006.0725
    [21]
    糜万鑫, 曹丽丽, 楚司祺, 等. 绿色荧光粉Sr 3P 4O 13: Ce 3+, Tb 3+的发光特性及Ce 3+→Tb 3+能量传递机理[J]. 光学学报,2019,39(8):0816002. doi:10.3788/AOS201939.0816002

    MI W X, CAO L L, CHU S Q, et al. Luminescence properties and energy transfer mechanism of Sr 3P 4O 13: Ce 3+, Tb 3+green phosphors[J]. Acta Optica Sinica, 2019, 39(8): 0816002. (in Chinese) doi:10.3788/AOS201939.0816002
    [22]
    于汀, 高明燕, 宋岩, 等. Dy 3+, Eu 3+共掺的LiGd(MoO 4) 2单一相荧光粉的合成、发光及能量传递[J]. 无机化学学报,2018,34(5):857-863. doi:10.11862/CJIC.2018.116

    YU T, GAO M Y, SONG Y, et al. Synthesis, luminescence and energy transfer of Dy 3+and Eu 3+co-doped LiGd(MoO 4) 2single-phase phosphors[J]. Chinese Journal of Inorganic Chemistry, 2018, 34(5): 857-863. (in Chinese) doi:10.11862/CJIC.2018.116
    [23]
    苏小娜, 万英, 周芷萱, 等. Na 2CaSiO 4: Sm 3+, Eu 3+荧光粉的发光特性和能量传递[J]. 物理学报,2017,66(23):230701. doi:10.7498/aps.66.230701

    SU X N, WAN Y, ZHOU ZH X, et al. Luminescence properties and energy transfer of Na 2CaSiO 4: Sm 3+, Eu 3+phosphor[J]. Acta Physica Sinica, 2017, 66(23): 230701. (in Chinese) doi:10.7498/aps.66.230701
    [24]
    BLASSE G. Energy transfer in oxidic phosphors[J]. Physics Letters A, 1968, 28(6): 444-445. doi:10.1016/0375-9601(68)90486-6
    [25]
    XIE A, YUAN X M, SHI Y, et al. Photoluminescence characteristics of energy transfer between Eu 3+and Bi 3+in LiEu 1−xBi x(WO 4) 0.5(MoO 4) 1.5[J]. Journal of the American Ceramic Society, 2009, 92(10): 2254-2258. doi:10.1111/j.1551-2916.2009.03195.x
    [26]
    陈彩花, 杨国辉, 梁利芳, 等. 溶胶凝胶法合成CaYAlO 4: Mn 4+红色荧光粉及其荧光性能研究[J]. 发光学报,2017,38(5):567-573. doi:10.3788/fgxb20173805.0567

    CHEN C H, YANG G H, LIANG L F, et al. Luminescent properties of CaYAlO 4: Mn 4+red phosphors prepared by sol-gel method[J]. Chinese Journal of Luminescence, 2017, 38(5): 567-573. (in Chinese) doi:10.3788/fgxb20173805.0567
    [27]
    ZHANG Y, GONG W T, YU J J, et al. Multi-color luminescence properties and energy transfer behaviour in host-sensitized CaWO 4: Tb 3+, Eu 3+phosphors[J]. RSC Advances, 2016, 6(37): 30886-30894. doi:10.1039/C6RA01862A
    [28]
    REISFELD R, LIEBLICH-SOFFER N. Energy transfer from UO 2 2+to Sm 3+in phosphate glass[J]. Journal of Solid State Chemistry, 1979, 28(3): 391-395. doi:10.1016/0022-4596(79)90090-2
    [29]
    HUANG C H, CHEN T M. A novel single-composition trichromatic white-light Ca 3Y(GaO) 3(BO 3) 4: Ce 3+, Mn 2+, Tb 3+phosphor for UV-light emitting diodes[J]. The Journal of Physical Chemistry C, 2011, 115(5): 2349-2355. doi:10.1021/jp107856d
    [30]
    JHA K, JAYASIMHADRI M. Effective sensitization of Eu 3+and energy transfer in Sm 3+/Eu 3+co-doped ZPBT glasses for CuPc based solar cell and w-LED applications[J]. Journal of Luminescence, 2018, 194: 102-107. doi:10.1016/j.jlumin.2017.09.049
    [31]
    PAULOSE P I, JOSE G, THOMAS V, et al. Sensitized fluorescence of Ce 3+/Mn 2+system in phosphate glass[J]. Journal of Physics and Chemistry of Solids, 2003, 64(5): 841-846. doi:10.1016/S0022-3697(02)00416-X
  • 加载中

Catalog

    通讯作者:陈斌, bchen63@163.com
    • 1.

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(7)/Tables(1)

    Article views(990) PDF downloads(70) Cited by()
    Proportional views

    /

    Return
    Return
      Baidu
      map