Volume 16Issue 5
Sep. 2023
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YANG Tian-yue, GONG Ting, GUO Gu-qing, SUN Xiao-cong, TIAN Ya-li, QIU Xuan-bing, HE Qiu-sheng, GAO Xiao-ming, LI Chuan-liang. Design and achievement of a device for high-precision ammonia gas detection based on laser spectroscopy[J]. Chinese Optics, 2023, 16(5): 1129-1136. doi: 10.37188/CO.2023-0023
Citation: YANG Tian-yue, GONG Ting, GUO Gu-qing, SUN Xiao-cong, TIAN Ya-li, QIU Xuan-bing, HE Qiu-sheng, GAO Xiao-ming, LI Chuan-liang. Design and achievement of a device for high-precision ammonia gas detection based on laser spectroscopy[J].Chinese Optics, 2023, 16(5): 1129-1136.doi:10.37188/CO.2023-0023

Design and achievement of a device for high-precision ammonia gas detection based on laser spectroscopy

doi:10.37188/CO.2023-0023
Funds:Supported by National Natural Science Foundation of China (No. U1810129, No. 52076145, No. 12304403); Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Province (No. 20230031); Shanxi Scholarship Council of China (No.2023-151); Fundamental Research Program of Shanxi Province (No. 202203021222204); Taiyuan University of Science and Technology Scientific Research Initial Funding (No. 20222008, No. 20222132); Transformation of Scientific and Technological Achievements Fund of Shanxi Province (No. 201904D131025)
More Information
  • Corresponding author:clli@tyust.edu.cn
  • Received Date:04 Feb 2023
  • Rev Recd Date:24 Feb 2023
  • Accepted Date:13 Apr 2023
  • Available Online:13 Apr 2023
  • Ammonia emission will cause harm to the environment and human health, so it is particularly important that the ammonia concentrations are measured with high precision. Off-Axis Integrating Cavity Output Spectroscopy (OA-ICOS), which has the advantages of high sensitivity and high response speed, is used to design a high-precision ammonia detection device. The gas absorption cell is composed of two high reflection mirrors with a reflectivity of 99.99%, and the base length of the optical resonator is 30 cm. Finally, an optical path of nearly 3000 m was realized. The Distributed Feedback Laser (DFB) with a central wavelength of 1528 nm is tuned to 6548.611 cm−1and 6548.798 cm−1. The concentration of NH3is changed from 1×10−5to 5×10−5and is detected under an atmospheric pressure of 18.6 kPa at room temperature. The measurement results show that the linear fit R 2between NH3concentration and signal amplitude can reach 0.99979. The Allan variance is used to analyze the experimental data, and the minimum detection limit of the system can reach 7×10−9at 103 s. The experimental results show that the detection device has good stability and high sensitivity, meets the demand for the high-precision detection of ammonia gas, and also provides technical experience for the domestic independent research and development of high-precision detection equipment for trace gases.

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  • [1]
    赵琳, 刘庆岭, 周伟, 等. 工业烟气脱硝技术国内外研究进展[J]. 化学试剂,2021,43(6):747-756.

    ZHAO L, LIU Q L, ZHOU W, et al. Research progress of industrial flue gas denitrification technology[J]. Chemical Reagents, 2021, 43(6): 747-756. (in Chinese)
    [2]
    LI SH W, CHANG M H, LI H M, et al. Chemical compositions and source apportionment of PM 2.5during clear and hazy days: seasonal changes and impacts of Youth Olympic Games[J]. Chemosphere, 2020, 256: 127163. doi:10.1016/j.chemosphere.2020.127163
    [3]
    李星国. 氢能的发展机遇与面临的挑战[J]. 应用化学,2022,39(7):1157-1166.

    LI X G. Development opportunities and challenges of hydrogen energy[J]. Chinese Journal of Applied Chemistry, 2022, 39(7): 1157-1166. (in Chinese)
    [4]
    程军杰, 曹智, 杨灿然, 等. 便携式远程 诱导击穿光谱系统及其定量分析性能[J]. 应用化学,2022,39(9):1447-1452.

    CHENG J J, CAO ZH, YANG C R, et al. Quantitative analysis with a portable remote laser-induced breakdown spectroscopy system[J]. Chinese Journal of Applied Chemistry, 2022, 39(9): 1447-1452. (in Chinese)
    [5]
    唐连波, 付大友, 陈琦, 等. 碳量子点增强气液相化学发光检测二氧化碳[J]. 应用化学,2022,39(8):1294-1302.

    TANG L B, FU D Y, CHEN Q, et al. Enhanced gas-liquid chemiluminescence by carbon dots for determination of carbon dioxide[J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1294-1302. (in Chinese)
    [6]
    王磊, 宦克为, 刘小溪, 等. 基于卷积神经网络的近红外光谱全流程分析模型研究[J]. 分析化学,2022,50(12):1918-1926.

    WANG L, HUAN K W, LIU X X, et al. Full-range analysis model of near infrared spectroscopy based on convolutional neural network[J]. Chinese Journal of Analytical Chemistry, 2022, 50(12): 1918-1926. (in Chinese)
    [7]
    李岩, 祁昱, 李赫. 拉曼光谱在感染性疾病诊断中的应用进展[J]. 分析化学,2022,50(3):317-326.

    LI Y, QI Y, LI H. Advances of Raman spectroscopy in diagnosis of infectious diseases[J]. Chinese Journal of Analytical Chemistry, 2022, 50(3): 317-326. (in Chinese)
    [8]
    黄慧, 周亦辰, 彭宇, 等. 基于量子级联 器中红外光谱技术的幽门螺旋杆菌呼气诊断的可行性研究[J]. 分析化学,2022,50(9):1328-1335.

    HUANG H, ZHOU Y CH, PENG Y, et al. Feasibility study of breath diagnosis in Helicobacter pyloribased on quantum cascade laser mid-infrared spectroscopy[J]. Chinese Journal of Analytical Chemistry, 2022, 50(9): 1328-1335. (in Chinese)
    [9]
    POGÁNY A, WAGNER S, WERHAHN O, et al. Development and metrological characterization of a Tunable Diode Laser Absorption Spectroscopy (TDLAS) spectrometer for simultaneous absolute measurement of carbon dioxide and water vapor[J]. Applied Spectroscopy, 2015, 69(2): 257-268. doi:10.1366/14-07575
    [10]
    DONG L, TITTEL F K, LI CH G, et al. Compact TDLAS based sensor design using interband cascade lasers for mid-IR trace gas sensing[J]. Optics Express, 2016, 24(6): A528-A535. doi:10.1364/OE.24.00A528
    [11]
    朱宝余, 孙成勋, 王兰, 等. 氨气检测仪研究现状[J]. 化工进展,2017,36(S1):27-33.

    ZHU B Y, SUN CH X, WANG L, et al. Research status of ammonia gas detector[J]. Chemical Industry and Engineering Progress, 2017, 36(S1): 27-33. (in Chinese)
    [12]
    FENG SH L, QIU X B, GUO G Q, et al. Palm-sized laser spectrometer with high robustness and sensitivity for trace gas detection using a novel double-layer toroidal cell[J]. Analytical Chemistry, 2021, 93(10): 4552-4558. doi:10.1021/acs.analchem.0c04995
    [13]
    SHAO L G, CHEN J J, WANG K Y, et al. Highly precise measurement of atmospheric N 2O and CO using improved White cell and RF current perturbation[J]. Sensors and Actuators B: Chemical, 2022, 352: 130995. doi:10.1016/j.snb.2021.130995
    [14]
    ZHANG L W, PANG T, ZHANG Z R, et al. A novel compact intrinsic safety full range Methane microprobe sensor using "trans-world" processing method based on near-infrared spectroscopy[J]. Sensors and Actuators B: Chemical, 2021, 334: 129680. doi:10.1016/j.snb.2021.129680
    [15]
    GUO Y CH, QIU X B, LI N, et al. A portable laser-based sensor for detecting H 2S in domestic natural gas[J]. Infrared Physics& Technology, 2020, 105: 103153.
    [16]
    TIAN J F, ZHAO G, FLEISHER A J, et al. Optical feedback linear cavity enhanced absorption spectroscopy[J]. Optics Express, 2021, 29(17): 26831-26840. doi:10.1364/OE.431934
    [17]
    CLAPS R, ENGLICH F V, LELEUX D P, et al. Ammonia detection by use of near-infrared diode-laser-based overtone spectroscopy[J]. Applied Optics, 2001, 40(24): 4387-4394. doi:10.1364/AO.40.004387
    [18]
    MILLER D J, SUN K, TAO L, et al. Open-path, quantum cascade-laser-based sensor for high-resolution atmospheric ammonia measurements[J]. Atmospheric Measurement Techniques, 2014, 7(1): 81-93. doi:10.5194/amt-7-81-2014
    [19]
    GUO X Q, ZHENG F, LI CH L, et al. A portable sensor for in-situ measurement of ammonia based on near-infrared laser absorption spectroscopy[J]. Optics and Lasers in Engineering, 2019, 115: 243-248. doi:10.1016/j.optlaseng.2018.12.005
    [20]
    TELFAH H, PAUL A C, LIU J J. Aligning an optical cavity: with reference to cavity ring-down spectroscopy[J]. Applied Optics, 2020, 59(30): 9464-9468. doi:10.1364/AO.405189
    [21]
    BAER D S, PAUL J B, GUPTA M, et al. Sensitive absorption measurements in the near-infrared region using off-axis integrated-cavity-output spectroscopy[J]. Applied Physics B, 2002, 75(2-3): 261-265. doi:10.1007/s00340-002-0971-z
    [22]
    贾慧, 郭晓勇, 蔡廷栋, 等. 1.531μm附近NH 3分子痕量探测[J]. 光谱学与光谱分析,2009,29(12):3173-3176. doi:10.3964/j.issn.1000-0593(2009)12-3173-04

    JIA H, GUO X Y, CAI T D, et al. Trace detection of ammonia at 1.531 μm[J]. Spectroscopy and Spectral Analysis, 2009, 29(12): 3173-3176. (in Chinese) doi:10.3964/j.issn.1000-0593(2009)12-3173-04
    [23]
    王坤阳. 基于离轴积分腔光谱大气CO 2和CH 4高精度测量技术研究[D]. 合肥: 中国科学技术大学, 2021.

    WANG K Y. In-site measurement of CO 2and CH 4in atmosphere using off-axis integrated cavity spectroscopy[D]. Hefei: University of Science and Technology of China, 2021. (in Chinese)
    [24]
    FIEDLER S E, HESE A, RUTH A A. Incoherent broad-band cavity-enhanced absorption spectroscopy[J]. Chemical Physics Letters, 2003, 371(3-4): 284-294. doi:10.1016/S0009-2614(03)00263-X
    [25]
    袁子豪, 黄印博, 钟磬, 等. V形结构离轴积分腔吸收光谱测量装置设计与研究[J]. 中国 ,2023,50(18):1811001.

    YUAN Z H, HUANG Y B, ZHONG Q, et al. Design and study of V-shaped structure off-axis integrated cavity absorption spectroscopy[J]. Chinese Journal of Lasers, 2023, 50(18): 1811001. (in Chinese)
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